83379-16-2

Basic information

• Product Name: Cyclohexanone, 3,3,5,5-tetramethyl-4-(1-methylethenyl)-
• CAS NO: 83379-16-2
• Molecular Formula: C13H22O
• Molecular Weight: 194.317
• Mol File: 83379-16-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 3,3,5,5-tetramethyl-4-(1-methylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 3,3,5,5-tetramethyl-4-(1-methylethenyl)-(83379-16-2)
• EPA Substance Registry System: Cyclohexanone, 3,3,5,5-tetramethyl-4-(1-methylethenyl)-(83379-16-2)

Safety Data

• Hazardous Substances Data: 83379-16-2(Hazardous Substances Data)

Upstream product

• 83379-10-6 1,1,3,3-tetramethyl-5-methylene-2-(1-methylethenyl)cyclohexane 
• 84602-70-0 1,3,3,5,5-Pentamethyl-4-(1-methylethenyl)chlorocyclohexane 
• 113831-05-3 cis-1-hydroxymethyl-3,3,5,5-tetramethyl-4-(1-methylethenyl)cyclohexane 
• 68930-33-6 tetramethyl-limonene (3,3,5,5-tetramethyl-p-mentha-1,8-diene) 

Downstream Products

• 16556-46-0 3,3,5,5-Tetramethyl-4-acetyl-1-cyclohexanon 
• 83379-14-0 cis-1,3,3,5,5-pentamethyl-4-(1-methylethenyl)cyclohexan-1-ol 
• 113831-10-0 (Z)-1-(3-hydroxypropyl)-3,3,5,5-tetramethyl-4-(1-methylethenyl)-1-cyclohexanol 
• 113831-25-7 (Z)-1-(3-hydroxy-1-propynyl)-3,3,5,5-tetramethyl-4-(1-methylethenyl)-1-cyclohexanol 

Relevant articles and documents

Regio- and Stereoselective Transformations of 3,3,5,5-Tetramethylcyclohexane Derivatives Oxygenations, Annulations, and SN2'-Reactions

Hydroboration of TM-Δ1,7-methadiene (4) (TM = tetramethyl) with 9-BBN gave TM-cis-shisool (cis-5), which was converted into TM-trans-shisool (trans-5) via the aldehyde cis-7, base-catalyzed epimerization to trans-7, and finally LiAlH4 reduction

Homologues of Monocyclic Monoterpenes. Tetramethylated Derivatives of Carvone, Carveol, β-Terpineol, Sobrerol, and Related Compounds

Epoxidation of tetramethyllimonene (1) gave monoepoxide 2t, which was opened regioselectively to endo and exo tetramethylated trans-carveols 3t and 5t, respectively.The alcohols were further oxidized to tetramethylcarvone (4) and its unstable exocyclic is