83565-90-6

Basic information

• Product Name: Benzene, [(3-methyl-3-nitro-4-phenylbutyl)sulfinyl]-
• CAS NO: 83565-90-6
• Molecular Formula: C17H19NO3S
• Molecular Weight: 317.409
• Mol File: 83565-90-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [(3-methyl-3-nitro-4-phenylbutyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(3-methyl-3-nitro-4-phenylbutyl)sulfinyl]-(83565-90-6)
• EPA Substance Registry System: Benzene, [(3-methyl-3-nitro-4-phenylbutyl)sulfinyl]-(83565-90-6)

Safety Data

• Hazardous Substances Data: 83565-90-6(Hazardous Substances Data)

Upstream product

• 17322-34-8 (2-nitropropyl)benzene 
• 20451-53-0 Phenyl vinyl sulfoxide 

Downstream Products

• 40296-93-3 (Z,E)-2-methyl-1-phenylbut-2-ene 
• 1647-06-9 (2-methylbuta-2,3-dien-1-yl)benzene 
• 83659-69-2 3-methyl-3-nitro-4-phenyl-1-butene 

Relevant articles and documents

New Synthetic Methods. Conjugate Addition of Alkyl Groups to Electron Deficient Olefins with Nitroalkanes as Alkyl Anion Equivalents

The sequence of the Michael addition of nitroalkanes and denitration from the adduct provides a new and general method for conjugate addition of primary and secondary alkyl groups to electron deficient olefins such as α,β-unsaturated aldehydes, ketones, esters, nitriles, sulfoxides, and sulfones.

CONJUGATE ADDITION OF ALKYL GROUPS TO α,β-UNSATURATED SULFOXIDES VIA MICHAEL ADDITION OF NITROPARAFFINS AND SUBSEQUENT DENITRATION WITH TRIBUTYLTIN HYDRIDE

Michael addition of nitroparaffins to α,β-unsaturated sulfoxides is well effected in the presence of DBU.The nitro group in the adduct is replaced by hydrogen with Bu3SnH without influence to the sulfinyl function.The overall reactions provide an efficien