83960-80-9Relevant articles and documents
Synthetic Investigations on Illudinine: A New Synthesis of Methyl 8-Methoxy-2,2-dimethyl-7-oxo-1,2,3,5,6,7-hexahydro-s-indacene-4-carboxylate
Girija, Talupuru,Shanker, P. Sathya,Rao, G. S. R. Subba
, p. 1467 - 1471 (2007/10/02)
A new strategy for the total synthesis of methyl 8-methoxy-2,2-dimethyl-7-oxo-1,2,3,5,6,7,-hexahydro-s-indacene-4-carboxylate 4, a key intermediate in the synthesis of illudalanes, is reported.The key step in this strategy is a new method of preparation o
BORON ANNULATION: SYNTHESIS OF TRANS-DECALIN NATURAL PRODUCT SYNTHONS
Reichel, Curtis J.,Bryson, Thomas A.
, p. 277 - 280 (2007/10/02)
Boron annulation of olefines 3, 4 and 14 has afforded decalin synthons 1 and 2 and perhydrophenanthrone 15, respectively.The A, B ring juncture of 15 and the ring systems of 1 and 2 were found to be trans.