83999-46-6

Basic information

• Product Name: 2-Hydroxy-2,6,6-trimethyl-cyclohex-3-enone
• CAS NO: 83999-46-6
• Molecular Weight: 154.209
• Mol File: 83999-46-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Hydroxy-2,6,6-trimethyl-cyclohex-3-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hydroxy-2,6,6-trimethyl-cyclohex-3-enone(83999-46-6)
• EPA Substance Registry System: 2-Hydroxy-2,6,6-trimethyl-cyclohex-3-enone(83999-46-6)

Safety Data

• Hazardous Substances Data: 83999-46-6(Hazardous Substances Data)

Upstream product

• 83999-45-5 2,6,6-Trimethyl-1-(trimethylsiloxy)-1,3-cyclohexadiene 

Downstream Products

• 17063-17-1 dihydroactinidiolide 
• 83999-47-7 2-Acetoxy-2,6,6-trimethyl-3-cyclohexen-1-one 

Relevant articles and documents

Oxidation of Enol Silyl Ethers: Preparation of Aeginetolide, Dihydroactinidiolide, and Actinidiolide

The preparation of the C11-terpenic lactones aeginetolide (1), dihydroactinidiolide (2), and actinidiolide (3) by using 1,3,3-trimethyl-2-(trimethylsiloxy)cyclohexene (9) as a common precursor is discussed.The key steps in the synthetic route involve the sequential m-chloroperbenzoic acid (MCPBA) oxidation and acetylation of 9 and of the siloxy diene 13 derived from 9.