84034-62-8

Basic information

• Product Name: N-((1R,2S,3R,4R,5R)-3-hydroxy-2-(trityloxy)-6,8-dioxabicyclo[3.2.1]octan-4-yl)acetamide
• Synonyms: N-((1R,2S,3R,4R,5R)-3-hydroxy-2-(trityloxy)-6,8-dioxabicyclo[3.2.1]octan-4-yl)acetamide
• CAS NO: 84034-62-8
• Molecular Weight: 445.515
• Mol File: 84034-62-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-((1R,2S,3R,4R,5R)-3-hydroxy-2-(trityloxy)-6,8-dioxabicyclo[3.2.1]octan-4-yl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-((1R,2S,3R,4R,5R)-3-hydroxy-2-(trityloxy)-6,8-dioxabicyclo[3.2.1]octan-4-yl)acetamide(84034-62-8)
• EPA Substance Registry System: N-((1R,2S,3R,4R,5R)-3-hydroxy-2-(trityloxy)-6,8-dioxabicyclo[3.2.1]octan-4-yl)acetamide(84034-62-8)

Safety Data

• Hazardous Substances Data: 84034-62-8(Hazardous Substances Data)

Upstream product

• 37042-52-7 N-((1R,2S,3R,4R,5R)-2,3-dihydroxy-6,8-dioxabicyclo[3.2.1]octan-4-yl)acetamide 
• 76-84-6 triphenylmethyl alcohol 
• 7512-17-6 N-Acetyl-D-glucosamine 
• 115726-23-3 triphenylmethyl trifluoromethanesulfonate 
• 50604-71-2 3,4-Di-O-acetyl-2-acetylamino-1,6-anhydro-2-deoxy-β-D-glucopyranose 
• 76-83-5 trityl chloride 

Downstream Products

• 291776-23-3 1,6-anhydro-2-acetamido-3-O-acetyl-2-deoxy-4-O-trityl-β-D-glucopyranose 
• 50604-73-4 2-Acetamido-1,6-anhydro-3-O-benzyl-2-desoxy-β-D-glucopyranose 
• 291776-21-1 1,6-anhydro-2-acetamido-3-O-benzoyl-2-deoxy-4-O-trityl-β-D-glucopyranose 

Relevant articles and documents

An efficient synthesis of 1,6-anhydro-N-acetylmuramic acid from N-acetylglucosamine

A novel synthesis of 1,6-anhydro-N-acetylmuramic acid is described, which proceeds in only five steps from the cheap starting material N-acetylglucosamine. This efficient synthesis should enable future studies into the importance of 1,6-anhydromuramic acid in bacterial cell wall recycling processes.

1,6-Anhydro-N-acetyl-β-D-glucosamine in the oligosaccharide syntheses: I. Synthesis of 3-acetate and 3-benzoate of 1,6-anhydro-N-acetyl-β-D-glucosamine via the 4-O-trityl derivative

3-O-Acetyl and 3-O-benzoyl derivatives of 1,6-anhydro-N-acetyl-β-D-glucosamine were synthesized via its selective tritylation followed by the 3-O-acylation and removal of the trityl protective group. Tritylium trifluoromethanesulfonate, which can easily be prepared by mixing solutions of triphenylcarbinol and trimethylsilyl trifluoromethanesulfonate in an equimolar ratio, was suggested as a reagent for the effective tritylation of a secondary hydroxyl group.