84538-49-8Relevant articles and documents
Photoreactive Composition, Reaction Product, and Method of Producing Reaction Product
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Paragraph 0342-0350, (2021/08/20)
A photoreactive composition including a base-reactive compound, a photobase generator that is represented by the following Formula (1) and that generates a base when irradiated with light, and at least one compound selected from the group consisting of a
Gold-catalyzed amide synthesis from aldehydes and amines in aqueous medium
Li, Gai-Li,Kung, Karen Ka-Yan,Wong, Man-Kin
supporting information; experimental part, p. 4112 - 4114 (2012/06/16)
An efficient gold-catalyzed amide synthesis from aldehydes and amines in aqueous medium under mild reaction conditions has been developed.
Effect of Nucleophilicity and Leaving Group Ability on the SN2 Reactions of Amines with (Acyloxy)alkyl α-Halides: A Product Distribution Study
Sloan, Kenneth B.,Koch, Suzanne A. M.
, p. 635 - 640 (2007/10/02)
The course of the reaction of amines with (acyloxy)alkyl α-halides has been found to depend on the nucleophilicity of the amines and the leaving group ability of the halides.More nucleophilic amines tended to give acylated products 2 from the reaction while less nucleophilic amines gave alkylated products 3.The use of a better leaving group also tended to favor the formation of a greater amount of alkylated product.These results have been compared to the observations of Westaway on the effect of leaving group ability and nucleophilicity on the bond lengths in the transit ion state of SN2 reactions.In addition, secondary amines have been shown to cause the rearrangement of 2-formylbenzamides to 3-amino-1(3H)-isobenzofuranones.