84623-44-9

Basic information

• Product Name: fac-Cl(ttp)ruthenium acetate
• CAS NO: 84623-44-9
• Molecular Weight: 758.179
• Mol File: 84623-44-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: fac-Cl(ttp)ruthenium acetate(CAS DataBase Reference)
• NIST Chemistry Reference: fac-Cl(ttp)ruthenium acetate(84623-44-9)
• EPA Substance Registry System: fac-Cl(ttp)ruthenium acetate(84623-44-9)

Safety Data

• Hazardous Substances Data: 84623-44-9(Hazardous Substances Data)

Relevant articles and documents

Synthesis and Characterization of Ruthenium Acetate Complex Containing Triphosphines

A series of ruthenium(II) acetate complexes were synthesized and characterized by31P{1H},1H, and13C{1H} NMR and IR spectroscopy. Treatment of RuCl2(Cyttp) (Cyttp = PhP(CH2CH2CH2P(c-C6H11)2)2) with 1 equiv of AgO2CMe at room temperature gives mer-RuCl(O2CMe)(Cyttp) and with excess NaO2CMe in refluxing methanol produces fac-RuCl(O2CMe)(Cyttp). fac-RuCl(O2CMe)(ttp) (ttp = PhP(CH2CH2CH2PPh2)2) was isolated when (RuCl2(ttp))xwas treated either with 1 equiv of AgO2CMe at room temperature or with excess NaO2CMe in refluxing methanol. Reaction of (RuCl2(ttp))xwith excess AgO2CMe at room temperature gives fac-Ru(O2CMe)2(ttp). The structure of fac-RuCl(O2CMe)(Cyttp) was determined by X-ray diffraction. fac-RuCl(O2CMe)(Cyttp)·CH3OH crystallized in the space group P21/c with cell parameters a = 17.534 (6) A?, b = 10.371 (4) A?, c = 22.983 (8) A?, β = 92.35 (3)°, V = 4175.7 (20) A?3, and Z = 4 and with R(F) = 0.038 and Rw(F) = 0.040.