84799-67-7Relevant articles and documents
Total synthesis of (2Z)-[(4R,5R,6S)-6-(β-D-glucopyranosyloxy)-4,5- dihydroxycyclohex-2-en-1-ylidene]ethanenitrile, a cyanoglucoside from Ilex warburgii
Josien-Lefebvre, Delphine,Le Drian, Claude
, p. 19 - 30 (2007/10/03)
The total synthesis of the noncyanogenic cyanoglucoside 1, originally isolated from Ilex warburgii, was achieved in nine steps (9% overall yield), starting from an optically pure Diels-Alder adduct ((+)-3). The key step of the synthesis, the glycosidation