84817-45-8Relevant articles and documents
Generation of Nitrile Oxides via O-Tributylstannyl Aldoximes; Application to the Synthesis of Isoxazolines and Isoxazoles
Moriya, Osamu,Takenaka, Hideo,Iyoda, Masaichi,Urata, Yoshikiyo,Endo, Takeshi
, p. 413 - 418 (1994)
Nitrile oxides were generated readily by the reaction of aldoximes 1, with tert-butyl hypochlorite and bis(tributyltin) oxide.The reaction proceeded efficiently under mild conditions, in which O-stannylated aldoximes 2 are thought to be key intermediates.This reaction system was applicable to the one-pot syntheses of isoxazole derivatives 4 and 5 in the presence of dipolarophiles via a cycloaddition.
SYNTHESIS AND PROPERTIES OF AZOLS AND THEIR DERIVATIVES. PART VII. SYNTHESIS OF ACRYLONITRILE AND METHACRYLONITRILE N-OXIDES AND THEIR REACTIONS WITH ALKENES
Baranski, Andrzej
, p. 1189 - 1191 (2007/10/02)
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