850449-41-1

Basic information

• Product Name: 2-{[(E)-(S)-1-Hydroxymethyl-2-phenyl-ethylimino]-methyl}-phenol
• Synonyms: 2-{[(E)-(S)-1-Hydroxymethyl-2-phenyl-ethylimino]-methyl}-phenol
• CAS NO: 850449-41-1
• Molecular Weight: 255.316
• Mol File: 850449-41-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-{[(E)-(S)-1-Hydroxymethyl-2-phenyl-ethylimino]-methyl}-phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{[(E)-(S)-1-Hydroxymethyl-2-phenyl-ethylimino]-methyl}-phenol(850449-41-1)
• EPA Substance Registry System: 2-{[(E)-(S)-1-Hydroxymethyl-2-phenyl-ethylimino]-methyl}-phenol(850449-41-1)

Safety Data

• Hazardous Substances Data: 850449-41-1(Hazardous Substances Data)

Upstream product

• 3182-95-4 L-Phenylalaninol 
• 90-02-8 salicylaldehyde 
• 89-95-2 2-methyl-benzyl alcohol 

Relevant articles and documents

Asymmetric alkynyl additions to aldehydes catalyzed by tunable oxovanadium(V) complexes of Schiff bases of β-amino alcohols

The first example of asymmetric alkynyl additions to aldehydes catalyzed by oxovanadium(V) catalysts of tridentate Schiff bases of β-amino alcohols 3a-h is reported. Catalytic reactions employing the best-performing catalyst 3g furnish chiral propargyl alcohols in good to excellent enantioselectivities from 73% to 99% ee. Georg Thieme Verlag Stuttgart.

Substituent effects and mechanism elucidation of enantioselective sulfoxidation catalyzed by vanadium Schiff base complexes

The effects of substituents of the Schiff base ligands on oxovanadium-catalyzed enantioselective sulfoxidation were first systematically studied, and a rational mechanism of enantioselective sulfoxidation based on our experimental data and the reported da

A highly enantioselective Strecker reaction catalyzed by titanium-N-salicyl-β-aminoalcohol complexes

N-salicyl-β-amino alcohols 1 were synthesized and evaluated as ligands for catalytic asymmetric Strecker reactions. N-Benzhydrylaldimines derived from aromatic and aliphatic aldehydes reacted with TMSCN in the presence of 10 mol% of Ti-1 complex to give t