85055-59-0

Basic information

• Product Name: Benzene, (hexyltelluro)-
• CAS NO: 85055-59-0
• Molecular Formula: C12H18Te
• Molecular Weight: 289.875
• Mol File: 85055-59-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, (hexyltelluro)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (hexyltelluro)-(85055-59-0)
• EPA Substance Registry System: Benzene, (hexyltelluro)-(85055-59-0)

Safety Data

• Hazardous Substances Data: 85055-59-0(Hazardous Substances Data)

Upstream product

• 3839-35-8 4-methylbenzenesulfonic acid n-hexylester 
• 32294-60-3 diphenyl ditelluride 
• 638-45-9 1-Iodohexane 
• 17774-09-3 n-hexyl mercury chloride 
• 55482-88-7 cyclohexyldihexylborane 
• 16156-50-6 n-hexyl methanesulfonate 
• 1188-92-7 Trihexylboran; Tri-n-hexylbor 
• 52251-52-2 (dicyclohexyl)hexylborane 

Downstream Products

• 92-52-4 biphenyl 
• 65-85-0 benzoic acid 

Relevant articles and documents

A new method for the synthesis of organotellurium compounds by the use of reductive cleavage of the tellurium-tellurium bond with lanthanum metal

It was confirmed that lanthanum metal is an efficient reagent for the reductive cleavage of the tellurium-tellurium bond of ditelluride. Alkyl phenyl tellurides were prepared by the reaction of diphenyl ditelluride with primary and secondary alkyl halides

Nucleophilic Reactions of Acetals, Alkyl Sulfonates, and Oxiranes with Diisobutylaluminum Benzenetellurolate

Diisobutylaluminum benzenetellurolate was proved to be an effective nucleophilic reagent toward acetals, alkyl sulfonates, and oxiranes to give the corresponding tellurides.These reactions showed the characteristics of an SN2 type.When the substitution reactions were sterically hindered, olefins and allylic alcohols were obtained from alkyl sulfonates and oxiranes, respectively.

Reactions of Alkylmercurials with Heteroatom-Centered Acceptor Radicals

The relative reactivities of alkylmercury halides toward PhS., PhSe., or I. decrease drastically from R = tert-butyl to R = sec-alkyl to R = n-butyl, indicative that R. is formed in the rate-determining step in the attack of these radicals upon RHgCl.The alkyl radicals thus formed will enter into chain reactions in which a heteroatom-centered radical (A.) is regenerated from substrates such as RS-SR, ArSe-SeAr, ArTe-TeAr, PhSe-SO2Ar, Cl-SO2Ph; ZCH=CHA (A = Cl, I, SPh, SO2Ph); or PhCCHA (A = I, SPh, SO2Ph). β-Styrenyl (PhCH=CHA, Ph2C=CHA) and β-phenethynyl (PhCCA) systems with A = I, Br, SO2Ph also enter into chain reactions with mercury(II) salts with the ligands PhS, PhSe, PhSO2, or (EtO)2PO.The relative reactivities of a series of reagents toward t-Bu. and of PhCH=CHA, Ph2C=CHA, and PhCCA toward c-C6H11. are reported as well as the regioselectivity of t-Bu. attack observed for 1,2-disubstituted ethylenes (ZCH=CHA) with Z and A from the group Ph, Cl, Br, I, SO2Ph, SPh, Bu3Sn.Reactions of (E)- and (Z)-PhCH=CHI or MeO2CCH=CHI with t-Bu. or c-C6H11. occurred in a regioselective and stereospecific (retention) manner.Reactions of (E)- and (Z)-ClCH=CHCl occurred in a nonstereospecific manner in which the E/Z product ratio increased with the bulk of the attacking radical.A similar effect on the E/Z product ratios was observed for (Z)-MeO2CCH=CHCl.