85100-77-2Relevant articles and documents
One-pot water-free ionic liquids synthesis using trialkyl orthoesters
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Paragraph 0049-0052, (2016/10/10)
The present invention relates to a manufacturing method of an ionic liquid, including a step of manufacturing an amine based compound or a heterocyclic compound including alkylated nitrogen made by making a negative ion salt compound and trialkyl ortho esters react with at least one among heterocyclic compounds with nitrogen and amine based compounds.COPYRIGHT KIPO 2015
A general and direct synthesis of imidazolium ionic liquids using orthoesters
Kim, Do Joong,Oh, Kyung Hwan,Park, Jin Kyoon
supporting information, p. 4098 - 4101 (2014/11/07)
A general method to synthesize halide and halide-free ionic liquids was developed. Direct alkylation of imidazole and pyridine derivatives was performed in the presence of an acid using an orthoester as the alkyl donor yielding ionic liquid products. Residual Cl and water contents of the ionic liquids were determined by ion chromatography and a Karl-Fisher test. the Partner Organisations 2014.
Modelling catalytic turnover frequencies in ionic liquids: The determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-w-butyl-3- methylimidazolium hexafluorophosphate
Swiderski, Konrad,McLean, Andrew,Gordon, Charles M.,Vaughan
, p. 590 - 591 (2007/10/03)
The bimolecular rate constant for solvent displacement, k2, from [(C6H6)Cr(CO)2Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF 6], and is compared to that for the same process in cyclohexane and dichloroethane.