851189-86-1

Basic information

• Product Name: 1-(4-[(1,1-dimethylethyl)dimethylsilyloxy]-2,2,5,5-tetramethylcyclohex-3-enyl)ethanone
• Synonyms: 1-(4-[(1,1-dimethylethyl)dimethylsilyloxy]-2,2,5,5-tetramethylcyclohex-3-enyl)ethanone
• CAS NO: 851189-86-1
• Molecular Weight: 310.552
• Mol File: 851189-86-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(4-[(1,1-dimethylethyl)dimethylsilyloxy]-2,2,5,5-tetramethylcyclohex-3-enyl)ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-[(1,1-dimethylethyl)dimethylsilyloxy]-2,2,5,5-tetramethylcyclohex-3-enyl)ethanone(851189-86-1)
• EPA Substance Registry System: 1-(4-[(1,1-dimethylethyl)dimethylsilyloxy]-2,2,5,5-tetramethylcyclohex-3-enyl)ethanone(851189-86-1)

Safety Data

• Hazardous Substances Data: 851189-86-1(Hazardous Substances Data)

Upstream product

• 67170-56-3 3-methyl-1-oxocyclohex-2-en-4-acetic acid methyl ester 
• 130043-07-1 2-<(tert-butyldimethylsilyl)oxy>-4,4-dimethyl-1,3-butadiene 
• 141-79-7 4-methyl-pent-3-en-2-one 

Downstream Products

• 16556-46-0 3,3,5,5-Tetramethyl-4-acetyl-1-cyclohexanon 

Relevant articles and documents

Stepwise acid-promoted double-Michael process: An alternative to Diels-Alder cycloadditions for hindered silyloxydiene-dienophile pairs

(Chemical Equation Presented) The hindered diene 1 reacts with 3-methylcyclohexenone 6 catalyzed by triflimide to produce the Mukaiyama Michael product 7 (low-temperature quenching) or the [4+2] cycloadduct 8 (quenching at 0°C). Reaction of the hindered d