852993-44-3

Basic information

• Product Name: [Pd(κ2-C,O-C(NH-t-Bu)CHC(O)Me)Cl(PPh3)]
• Synonyms: [Pd(κ2-C,O-C(NH-t-Bu)CHC(O)Me)Cl(PPh3)]
• CAS NO: 852993-44-3
• Molecular Weight: 544.369
• Mol File: 852993-44-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(κ2-C,O-C(NH-t-Bu)CHC(O)Me)Cl(PPh3)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(κ2-C,O-C(NH-t-Bu)CHC(O)Me)Cl(PPh3)](852993-44-3)
• EPA Substance Registry System: [Pd(κ2-C,O-C(NH-t-Bu)CHC(O)Me)Cl(PPh3)](852993-44-3)

Safety Data

• Hazardous Substances Data: 852993-44-3(Hazardous Substances Data)

Upstream product

• 852993-24-9 [Pd2(CH2C(O)Me)2(μ-Cl)2(tert-butyl isocyanide)2] 
• 852993-26-1 [Pd2(κ2-C,O-C(NH-t-Bu)CHC(O)Me)2(μ-Cl)2] 
• 603-35-0 triphenylphosphine 

Downstream Products

• 13965-03-2 bis-triphenylphosphine-palladium(II) chloride 

Relevant articles and documents

Reactivity of [Pd{CH2C(O)Me}Cl]Mn toward isocyanides

The capacity of [Pd{CH2C(O)Me}Cl]n to prepare chloro-monoacetonyl or monoacetonyl palladium (II) complexes was analyzed. The established synthetic procedures for these complexes invariably involve the presence of other strongly coordinated ligands. The thermal transformation of these compounds into C-palladated β-ketoenamine complexes resulting from insertion of one molecule of the isocyanide followed by a β-ketoimine to β-ketoenamine tautomerization processes. The resulting complexes were the first palladium compounds containing such ligands acting as a chelate.