853193-73-4

Basic information

• Product Name: (S)-2-Methyl-butyric acid (1S,4aR,7S,8S,8aS)-8-[(R)-3-(2-bromo-acetoxy)-5-hydroxy-pentyl]-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl ester
• CAS NO: 853193-73-4
• Molecular Weight: 473.448
• Mol File: 853193-73-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-Methyl-butyric acid (1S,4aR,7S,8S,8aS)-8-[(R)-3-(2-bromo-acetoxy)-5-hydroxy-pentyl]-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-Methyl-butyric acid (1S,4aR,7S,8S,8aS)-8-[(R)-3-(2-bromo-acetoxy)-5-hydroxy-pentyl]-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl ester(853193-73-4)
• EPA Substance Registry System: (S)-2-Methyl-butyric acid (1S,4aR,7S,8S,8aS)-8-[(R)-3-(2-bromo-acetoxy)-5-hydroxy-pentyl]-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl ester(853193-73-4)

Safety Data

• Hazardous Substances Data: 853193-73-4(Hazardous Substances Data)

Upstream product

• 632339-24-3 (R)-4-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxane 
• 185553-79-1 (R)-2-<2,2-dimethyl-1,3-dioxan-4-yl>ethan-1-ol 
• 81132-13-0 (S)-5-phenylmethoxypentane-1,3-diol 
• 853193-46-1 Bromo-acetic acid (R)-1-[2-((1S,2S,4aR,8S,8aS)-8-hydroxy-2-methyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl)-ethyl]-3-trityloxy-propyl ester 
• 853193-71-2 (1S,4aR,7S,8S,8aS)-8-((R)-3-Hydroxy-5-trityloxy-pentyl)-7-methyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ol 
• 853193-70-1 (4aR,7S,8S,8aS)-8-((R)-3-Hydroxy-5-trityloxy-pentyl)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-naphthalen-1-one 
• 853193-69-8 (12E,14E)-(R)-1,3-Bis-trimethylsilanyloxy-hexadeca-12,14-dien-6-yn-8-one 
• 853193-44-9 (R,6Z,12E,14E)-1,3-bis((trimethylsilyl)oxy)hexadeca-6,12,14-trien-8-one 
• 853193-67-6 (9E,11E)-1-((R)-2,2-Dimethyl-[1,3]dioxan-4-yl)-trideca-9,11-dien-3-yn-5-one 
• 853193-66-5 (9E,11E)-1-((R)-2,2-Dimethyl-[1,3]dioxan-4-yl)-trideca-9,11-dien-3-yn-5-ol 
• 853193-52-9 (4aR,7S,8S,8aS)-8-((R)-3,5-Dihydroxy-pentyl)-7-methyl-3,4,4a,7,8,8a-hexahydro-2H-naphthalen-1-one 
• 853193-68-7 (12E,14E)-(R)-1,3-Dihydroxy-hexadeca-12,14-dien-6-yn-8-one 
• 853193-64-3 Toluene-4-sulfonic acid 2-((S)-2,2-dimethyl-[1,3]dioxan-4-yl)-ethyl ester 
• 853193-65-4 (R)-4-But-3-ynyl-2,2-dimethyl-[1,3]dioxane 

Downstream Products

• 78366-44-6 (+)-dihydrocompactin 

Relevant articles and documents

Remote asymmetric induction in an intramolecular ionic Diels-Alder reaction: Application to the total synthesis of (+)-dihydrocompactin

The total synthesis of (+)-dihydrocompactin via an intramolecular ionic Diels-Alder reaction that proceeds with remote stereocontrol is described. This reaction proceeds by an intermediate vinyl-oxocarbenium ion (6), the conformational constraints of whic