85533-22-8Relevant articles and documents
TRANSFORMATIONS OF CYCLIC ORTHO MONO- AND DIESTERS BY THE ACTION OF FREE RADICALS IN THE LIQUID PHASE
Kostyukevich, L. L.,Pastuschenko, E. V.,Zlot-skii S. S.,Rakhmankulov, D. L.
, p. 127 - 132 (2007/10/02)
The homolytic liquid-phase reactions of 2-propoxy-1,3-dioxane, 1,2-di(1,3-dioxolan-2-yloxy)ethane, and 1,3-di(1,3-dioxan-2-yloxy)propane, initiated by tert-butoxyl radicals, were investigated.A mechanism is proposed for the formation of dipropylcarbonate, 1,3-dioxan-2-one, propylformate, propionaldehyde, and propane from 2-propoxy-1,3-dioxane.The kinetic parameters characterizing the rate and direction of the transformations were determined.It was found that the corresponding linear and cyclic carbonates are mainly formed from the ortho diesters.