85678-39-3

Basic information

• Product Name: 1-[4-(trimethylsilyl)-1,3-butadiyn-1-yl]cyclohexene
• Synonyms: 1-[4-(trimethylsilyl)-1,3-butadiyn-1-yl]cyclohexene
• CAS NO: 85678-39-3
• Molecular Weight: 202.371
• Mol File: 85678-39-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-[4-(trimethylsilyl)-1,3-butadiyn-1-yl]cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[4-(trimethylsilyl)-1,3-butadiyn-1-yl]cyclohexene(85678-39-3)
• EPA Substance Registry System: 1-[4-(trimethylsilyl)-1,3-butadiyn-1-yl]cyclohexene(85678-39-3)

Safety Data

• Hazardous Substances Data: 85678-39-3(Hazardous Substances Data)

Upstream product

• 931-49-7 1-ethenylcyclohexene 
• 1066-54-2 trimethylsilylacetylene 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 18243-59-9 (2-bromoethynyl)trimethylsilane 

Downstream Products

• 82936-58-1 1-(buta-1,3-diynyl)cyclohex-1-ene 
• 74751-57-8 di-cyclohex-1-enyl-octatetrayne 
• 1394290-90-4 1-(6,6,6-trifluorohexa-1,3-diyn-1-yl)cyclohex-1-ene 

Relevant articles and documents

Syntheses of trifluoroethylated unsymmetrical 1,3-diynes by using 1,1-dichloro-2,2,2-trifluoroethane

Copper-mediated reaction of terminal 1,3-diynes with 1,1-dichloro-2,2,2-trifluoroethane (CF3CHCl2) using ethanolamine as ligand gave trifluoroethylated unsymmetrical 1,3-diynes in moderate to good yields. The reaction were carried out under mild conditions, and were easy to operate. Aryl groups with weak electron-withdrawing group or electron-donating group, and alkyl substitutents at terminal 1,3-diynes were tolerated. Synthesis of a trifluoroethylated conjugated triyne by using this method was demonstrated. Further transformation of the trifluoroethylated unsymmetrical 1,3-diyne to provide trifluoroethyl-substituted 1,2,3-triazole and isoxazole as application examples were successfully realized.

A Convenient Synthesis of 1-Trimethylsilyl-1,3-diynes and their Conversion into Terminal 1,3-Diynes

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