85692-69-9Relevant articles and documents
Visible light photoredox catalyzed deprotection of 1,3-oxathiolanes
Yang, Mingyang,Xing, Zhimin,Fang, Bowen,Xie, Xingang,She, Xuegong
supporting information, p. 288 - 291 (2020/01/13)
An efficient visible light photoredox catalyzed aerobic deprotection of 1,3-oxathiolanes using organic dye Eosin Y as a photocatalyst is disclosed. The deprotection procedure features the use of a metal-free catalyst, mild conditions, a broad range of substrate scope, and good functional group tolerance. 35 examples were tested under the standard conditions and most of them afforded the deprotected products in modest to high yields.
Nitroaromatic bis(2-hydroxyethyl)dithioacetals and oxathioacetals using 2-mercaptoethanol in the presence of chlorosilanes
Papernaya, Lyubov K.,Shatrova, Alexandra A.,Albanov, Alexander I.,Klyba, Lyudmila V.,Levkovskaya, Galina G.
experimental part, p. 173 - 184 (2012/04/18)
Thioacetalization of the nitrobenzaldehydes with 2-mercaptoethanol is easily carried out in the presence of TMSCl and dichlorodimethylsilane without heating and using of additional solvent. The reaction direction is defined by the reagents ratio and led t
Deprotection of 1,3-oxathiolanes to carbonyl compounds with montmorillonite K10
Chauhan,Kumar, Anil,Sahoo
, p. 2635 - 2637 (2007/10/03)
Montmorillonite K10 has been used in the deprotection of different aromatic and aliphatic 1,3-oxathiolanes to the corresponding carbonyl compounds in 73 to 97% yields under mild and environmentally compatible conditions.
