85736-14-7

Basic information

• Product Name: (E)-1-(3-Chloro-phenyl)-4-hydroxy-4-methyl-pent-1-en-3-one
• Synonyms: (E)-1-(3-Chloro-phenyl)-4-hydroxy-4-methyl-pent-1-en-3-one
• CAS NO: 85736-14-7
• Molecular Weight: 224.687
• Mol File: 85736-14-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(3-Chloro-phenyl)-4-hydroxy-4-methyl-pent-1-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(3-Chloro-phenyl)-4-hydroxy-4-methyl-pent-1-en-3-one(85736-14-7)
• EPA Substance Registry System: (E)-1-(3-Chloro-phenyl)-4-hydroxy-4-methyl-pent-1-en-3-one(85736-14-7)

Safety Data

• Hazardous Substances Data: 85736-14-7(Hazardous Substances Data)

Upstream product

• 115-22-0 3-Hydroxy-3-methyl-2-butanone 
• 587-04-2 m-Chlorobenzaldehyde 

Relevant articles and documents

Stereoelectronic Control of Intramolecular Michael Addition Reactions

Concepts of stereoelectronic control lead to the conclusion that the 5-endo-trig ring closure of (E)-2-methyl-3-oxo-5-phenylpent-4-en-2-ol should be disfavored.However, the acid-catalyzed ring closure in trifluoroacetic acid occurs readily, suggesting an