85869-04-1

Basic information

• Product Name: Methanone, (4-chlorophenyl)(1-methyl-5-nitro-1H-imidazol-2-yl)-
• CAS NO: 85869-04-1
• Molecular Formula: C11H8ClN3O3
• Molecular Weight: 265.656
• Mol File: 85869-04-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanone, (4-chlorophenyl)(1-methyl-5-nitro-1H-imidazol-2-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (4-chlorophenyl)(1-methyl-5-nitro-1H-imidazol-2-yl)-(85869-04-1)
• EPA Substance Registry System: Methanone, (4-chlorophenyl)(1-methyl-5-nitro-1H-imidazol-2-yl)-(85869-04-1)

Safety Data

• Hazardous Substances Data: 85869-04-1(Hazardous Substances Data)

Upstream product

• 3034-42-2 1-methyl-5-nitro-1H-imidazole 
• 122-01-0 4-chloro-benzoyl chloride 

Downstream Products

• 85869-07-4 2-(p-chlorophenylcarbamoyl)-1-methyl-5-nitro-imidazole 
• 85869-06-3 (4-Chloro-phenyl)-(1-methyl-5-nitro-1H-imidazol-2-yl)-methanone oxime 

Relevant articles and documents

Nitroimidazoles: Part XII - Reaction of 1-Methyl-5-nitroimidazoles with Acid Chlorides

The aroylation of 1-methyl-5-nitroimidazole with aroyl chlorides in the presence of triethylamine leads to 2-aroyl-1-methyl-5-nitroimidazole(I).Beckmann rearrangement of the corresponding oximes (II) yield the anilides (III) as normal Beckmann products.Aroylation of I with p-nitrobenzoyl chloride yields besides the normal derivative (IVa), a minor product (IVB) formed by the attack of a second molecule of the nitroimidazole on the carbonyl carbon.Methyloxalyl chloride similarly yields two products, the major one being the 2-carbomethoxy derivative (VIA).