86042-28-6

Basic information

• Product Name: 1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-beta-D-ribofuranose
• Synonyms: 1,5-DI-O-(4-METHYLBENZOYL)-2,3-O-ISOPROPYLIDENE-BETA-D-RIBOFURANOSE;1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-β-D-ribofuranose;(3aR,4S,6R,6aR)-2,2-dimethyl-6-((4-methylbenzoyloxy)methyl)tetrahydrofuro[3,4-d][1,3]dioxol-4-yl 4-methylbenzoate;1,5-Di-O-toluoyl-2,3-O-isopropylidene-b-D-ribofuranose
• CAS NO: 86042-28-6
• Molecular Formula: C₂₄H₂₆O₇
• Molecular Weight: 426.46
• Mol File: 86042-28-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 541.3 °C at 760 mmHg
• Flash Point: 233.6 °C
• Appearance: /
• Density: 1.27 g/cm³
• Refractive Index: 1.583
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-beta-D-ribofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-beta-D-ribofuranose(86042-28-6)
• EPA Substance Registry System: 1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-beta-D-ribofuranose(86042-28-6)

Safety Data

• Hazardous Substances Data: 86042-28-6(Hazardous Substances Data)

Usage

General Description

1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-beta-D-ribofuranose is a chemical compound with a complex molecular structure. It is a derivative of ribofuranose, a type of sugar, and contains two 4-methylbenzoyl groups and an isopropylidene group. 1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-beta-D-ribofuranose has been studied for its potential applications in organic synthesis and medicinal chemistry. It may have uses in the development of new drugs or as a building block for the synthesis of other organic compounds. The chemical properties and potential uses of 1,5-Di-O-(4-methylbenzoyl)-2,3-O-isopropylidene-beta-D-ribofuranose make it an interesting and valuable compound for further research and development in the field of chemistry.

InChI:InChI=1/C24H26O7/c1-14-5-9-16(10-6-14)21(25)27-13-18-19-20(31-24(3,4)30-19)23(28-18)29-22(26)17-11-7-15(2)8-12-17/h5-12,18-20,23H,13H2,1-4H3/t18-,19-,20-,23+/m1/s1

Upstream product

• 67814-68-0 2,3-O-isopropylidene-D-ribofuranose 
• 874-60-2 4-methyl-benzoyl chloride 

Downstream Products

• 86042-31-1 1,2,3-tri-O-p-nitrobenzoyl-5-O-p-toluyl-β-D-ribofuranose 
• 86042-32-2 1,2,3-tri-O-benzoyl-5-O-p-toluyl-β-D-ribofuranose 
• 98807-28-4 4-Methyl-benzoic acid (3aR,4R,6aR)-6-(4-hydroxy-5-methyl-2-oxo-2H-pyrimidin-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 
• 98807-27-3 4-Methyl-benzoic acid (3aR,4R,6S,6aR)-6-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 
• 98807-31-9 4-Methyl-benzoic acid (3aR,4R,6R,6aR)-6-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 
• 98807-27-3 4-Methyl-benzoic acid (3aR,4R,6aR)-6-(4-hydroxy-2-oxo-2H-pyrimidin-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 
• 98807-29-5 4-Methyl-benzoic acid (3aR,4R,6S,6aR)-6-(4-benzoylamino-2-oxo-2H-pyrimidin-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 
• 98807-33-1 4-Methyl-benzoic acid (3aR,4R,6R,6aR)-6-(4-benzoylamino-2-oxo-2H-pyrimidin-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 
• 98807-29-5 4-Methyl-benzoic acid (3aR,4R,6aR)-6-(4-benzoylamino-2-oxo-2H-pyrimidin-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 
• 86042-29-7 1,2,3-tri-O-acetyl-5-O-p-toluyl-β-D-ribofuranose 

Relevant articles and documents

IMPROVED SYNTHESIS OF 2,5-ANHYDRO-D-ALLONITRILE

Two types of mixed ester of β-D-ribofuranose were synthesized.The first had the same groups attached to O-1, 2, and 3, and the second had the same groups attached to O-2,3 and 5.The three esters obtained in the highest yields, starting from D-ribose, were then converted into the halides and nitriles.Of the esters studied, the best suited for conversion into the nitrile was 1-O-acetyl-2,3,5-tri-O-p-toluyl-β-D-ribofuranose, which afforded 2,5-anhydro-3,4,6-tri-O-p-toluyl-D-allonitrile in 60percent yield.