860435-39-8

Basic information

• Product Name: 2-Bromo-4-tert-butyl-1-iodo-benzene
• Synonyms: 2-Bromo-4-tert-butyl-1-iodo-benzene
• CAS NO: 860435-39-8
• Molecular Formula: C₁₀H₁₂BrI
• Molecular Weight: 339.01075
• Mol File: 860435-39-8.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 282.0±28.0 °C(Predicted)
• Appearance: /
• Density: 1.744±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-Bromo-4-tert-butyl-1-iodo-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromo-4-tert-butyl-1-iodo-benzene(860435-39-8)
• EPA Substance Registry System: 2-Bromo-4-tert-butyl-1-iodo-benzene(860435-39-8)

Safety Data

• Hazardous Substances Data: 860435-39-8(Hazardous Substances Data)

Usage

General Description

2-Bromo-4-tert-butyl-1-iodo-benzene is a chemical compound with the molecular formula C10H12BrI. It is a substituted benzene derivative with bromine and iodine atoms attached to the benzene ring. The tert-butyl group is also attached to the benzene ring, contributing to its molecular structure. 2-Bromo-4-tert-butyl-1-iodo-benzene is used as an intermediate in organic synthesis and pharmaceutical research. It may also be used in the production of agrochemicals and other specialty chemicals. The presence of bromine and iodine atoms in its structure makes it a potentially useful reagent in various chemical reactions and processes. Safety precautions should be observed when handling and working with this compound due to its potential health and environmental hazards.

Upstream product

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Relevant articles and documents

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A series of four asymmetrically aryl-substituted 9,9′-spiro-9- silabifluorene (SSF) derivatives, 2,2′-di-tert-butyl-7,7′-diphenyl- 9,9′-spiro-9-silabifluorene (PhSSF), 2,2′-di-tert-butyl-7,7′- dipyridin-2-yl-9,9′-spiro-9-silabifluorene (PySSF), 2,2′-di-tert- butyl-7,7′-dibiphenyl-4-yl-9,9′-spiro-9-silabifluorene (BPhSSF), and 2,2′-di-tert-butyl-7,7′-bis(2′,2″-bipyridin-6-yl)-9, 9′-spiro-9-silabifluorene (BPySSF) are prepared through the cyclization of the corresponding 2,2′-dilithiobiphenyls with silicon tetrachloride. These novel spiro-linked silacyclopentadienes (siloles) form transparent and stable amorphous films with relatively high glass transition temperatures (Tg = 203-228°C). The absorbance spectrum of each compound shows a significant bathochromic shift relative to that of the corresponding carbon analogue as a result of the effective σ*-π* conjugation between the σ* orbital of the exocyclic Si-C bond and the π* orbital of the oligoarylene fragment. Solid-state films exhibit intense violet-blue emission (λPL = 398-415 nm) with high absolute photoluminescence quantum yields (ΦPL = 30-55%).