861392-01-0

Basic information

• Product Name: 1,1,3,3-tetramethyl-1,3-di[3,3-diethoxycarbonyl-4-(3-methoxyphenyl)-1-butenyl]disiloxane
• Synonyms: 1,1,3,3-tetramethyl-1,3-di[3,3-diethoxycarbonyl-4-(3-methoxyphenyl)-1-butenyl]disiloxane
• CAS NO: 861392-01-0
• Molecular Weight: 743.011
• Mol File: 861392-01-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1,3,3-tetramethyl-1,3-di[3,3-diethoxycarbonyl-4-(3-methoxyphenyl)-1-butenyl]disiloxane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,3,3-tetramethyl-1,3-di[3,3-diethoxycarbonyl-4-(3-methoxyphenyl)-1-butenyl]disiloxane(861392-01-0)
• EPA Substance Registry System: 1,1,3,3-tetramethyl-1,3-di[3,3-diethoxycarbonyl-4-(3-methoxyphenyl)-1-butenyl]disiloxane(861392-01-0)

Safety Data

• Hazardous Substances Data: 861392-01-0(Hazardous Substances Data)

Upstream product

• 861391-99-3 diethyl (1-dimethyl[phenyl]silylvinyl)(3-methoxybenzyl)malonate 

Relevant articles and documents

A novel approach towards dibenzylbutyrolactone lignans involving heck and radical reactions: Application to (±)-matairesinol synthesis

A highly regio- and stereoselective Heck reaction of iodoarenes with vinylated malonates, generated in situ by fluoride-induced protiodesilylation of alkenylsilanols/disiloxanes to give functionalized styrenes and 1,4-diaryl-1-butenes has been developed. The dibenzylbutyrolactone lignan skeletons have been achieved from 1,4-diaryl-1-butenes by two routes involving diastereoselective radical cyclization as the key step. This strategy has successfully been applied in the synthesis of (±)-matairesinol. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.