861909-30-0 Usage
Description
R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate is a hydrogenphosphate ester of 3,3'-bis(4-(1,1-dimethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diol with the molecular formula C46H48O4P. It is a chemical compound commonly used in organic synthesis and as a chiral ligand in asymmetric catalysis.
Uses
Used in Pharmaceutical Industry:
R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate is used as a chiral ligand in asymmetric catalysis for the production of chiral drugs. Its ability to induce chirality in reactions allows for the synthesis of enantiomerically pure compounds, which are essential in the development of effective and safe medications.
Used in Agrochemical Industry:
In the agrochemical industry, R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate is utilized as a chiral ligand in asymmetric catalysis for the production of chiral pesticides. The enantioselective synthesis of these compounds helps in creating more targeted and environmentally friendly pest control solutions.
Used in Organic Synthesis:
R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate is used as a reagent in organic synthesis, contributing to the formation of various complex organic molecules. Its versatility in reactions makes it a valuable tool for creating a wide range of chemical products.
Used in Synthesis of Optically Active Molecules:
R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate is employed in the synthesis of optically active molecules, which have unique properties due to their specific three-dimensional structures. These molecules have applications in various fields, including materials science, pharmaceuticals, and agrochemicals, where their distinct properties can be harnessed for specific uses.
Check Digit Verification of cas no
The CAS Registry Mumber 861909-30-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,6,1,9,0 and 9 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 861909-30:
(8*8)+(7*6)+(6*1)+(5*9)+(4*0)+(3*9)+(2*3)+(1*0)=190
190 % 10 = 0
So 861909-30-0 is a valid CAS Registry Number.
861909-30-0Relevant articles and documents
Enantioselective Oxidative Homocoupling and Cross-Coupling of 2-Naphthols Catalyzed by Chiral Iron Phosphate Complexes
Narute, Sachin,Parnes, Regev,Toste, F. Dean,Pappo, Doron
, p. 16553 - 16560 (2016/12/27)
Novel chiral iron phosphate complexes were prepared as catalysts for asymmetric oxidative coupling reactions. These catalysts were applied for the synthesis of enantio-enriched C1- and C2-symmetric BINOLs, in which the 3 and 3′ positions are available for chemical modifications. It was proposed that the reaction takes place via an oxidative radical-anion coupling mechanism. A destructive BINOL racemization that competes with the enantioselective oxidative coupling of 2-naphthols was revealed, thereby offering new insights into this highly important reaction.
Enantioselective organocatalytic fluorination-induced Wagner-Meerwein rearrangement
Romanov-Michailidis, Fedor,Guénée, Laure,Alexakis, Alexandre
, p. 9266 - 9270 (2013/09/12)
Cracked under strain: Strained allylic cyclobutanols and cyclopropanols readily undergo a ring expansion described by the title rearrangement. This reaction is promoted by catalytic amounts of 1 and displays high tolerance with respect to the substrate scope. The corresponding β-fluoro spiroketone products are isolated in high yields and with excellent stereoselectivities. EDG=electron-donating group, EWG=electron-withdrawing group. Copyright
Enantioselective direct aza hetero-Diels-Alder reaction catalyzed by chiral Bronsted acids
Liu, Hua,Cun, Lin-Feng,Mi, Ai-Qiao,Jiang, Yao-Zhong,Gong, Liu-Zhu
, p. 6023 - 6026 (2007/10/03)
(Chemical Equation Presented) The first chiral Bronsted acid-catalyzed asymmetric direct aza hetero-Diels-Alder reaction has been described. The phosphoric acids, prepared from binol and H8-binol derivatives, have shown catalytic ability for th