86295-95-6

Basic information

• Product Name: Methylene, chloro[4-(trifluoromethyl)phenyl]-
• CAS NO: 86295-95-6
• Molecular Formula: C8H4ClF3
• Molecular Weight: 192.568
• Mol File: 86295-95-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Methylene, chloro[4-(trifluoromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methylene, chloro[4-(trifluoromethyl)phenyl]-(86295-95-6)
• EPA Substance Registry System: Methylene, chloro[4-(trifluoromethyl)phenyl]-(86295-95-6)

Safety Data

• Hazardous Substances Data: 86295-95-6(Hazardous Substances Data)

Upstream product

• 1269766-22-4 C₈H₄ClF₃*C₉H₁₂O₃ 
• 115127-52-1 3-chloro-3-(4-trifluoromethylphenyl)diaziridine 

Downstream Products

• 1269766-22-4 C₈H₄ClF₃*C₉H₁₂O₃ 

Relevant articles and documents

Hammett analysis of a family of carbene-carbene complex equilibria

p-X-substituted phenylchlorocarbenes (X = NO2, CF3, Cl, H, Me, and MeO) form π-type complexes with trimethoxybenzene in pentane. The carbenes and complexes are in equilibrium, and logarithms of the measured equilibrium constants are well correlated by Hammett σp constants with ρ = 2.48. The carbene complexes are characterized by UV-vis spectroscopy, and computational analysis is afforded by DFT calculations.(Figure Presented)

HAMMETT ANALYSIS OF ABSOLUTE CARBENE ADDITION RATE CONSTANTS

Absolute rate constants were determined for the additions of 5 p-X-substituted ArCCl (X=CF3, Cl, H, CH3, CH3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ= +1.4 - 1.6.