86517-38-6Relevant articles and documents
Nucleophilic Addition of Trimethylsilylamines to 2-Halo-2-alkenals
Rulev,Kuznetsova,Mokov,Sherstyannikova,Keiko,Voronkov
, p. 26 - 28 (2007/10/03)
2-Halo-2-alkenals react with trimethylsilyl derivatives of secondary amines to give the products of 1,2- and 1,4-addition. Both the structure of the starting aldehyde and the nature of the substituent at the nitrogen atom are responsible for reaction selectivity.