86622-84-6

Basic information

• Product Name: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER
• Synonyms: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER
• CAS NO: 86622-84-6
• Molecular Formula: C₁₃H₁₅NO₄
• Molecular Weight: 249.2625
• Mol File: 86622-84-6.mol
• Article Data: 242

Chemical Properties

• Boiling Point: 355.13°C at 760 mmHg
• Flash Point: 143.705°C
• Appearance: /
• Density: 1.177g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.565
• CAS DataBase Reference: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER(86622-84-6)
• EPA Substance Registry System: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER(86622-84-6)

Safety Data

• Hazardous Substances Data: 86622-84-6(Hazardous Substances Data)

Usage

General Description

(E)-3-(4-nitro-phenyl)-acrylic acid butyl ester is a chemical compound with the molecular formula C14H15NO4. It is an ester derivative of (E)-3-(4-nitro-phenyl)-acrylic acid, which is a yellow crystalline solid with a molecular weight of 257. The butyl ester form of this compound is commonly used in the preparation of various organic compounds and can be used as a starting material for the synthesis of pharmaceuticals, agrochemicals, and other fine chemicals. It is also used in organic chemical synthesis and as a reagent in various chemical reactions due to its unique structural and chemical properties. Additionally, (E)-3-(4-nitro-phenyl)-acrylic acid butyl ester is known for its potential and proven applications in the field of material science and biochemistry.

InChI:InChI=1/C13H15NO4/c1-2-3-10-18-13(15)9-6-11-4-7-12(8-5-11)14(16)17/h4-9H,2-3,10H2,1H3/b9-6+

Upstream product

• 141-32-2 acrylic acid n-butyl ester 
• 100-00-5 4-chlorobenzonitrile 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 24067-17-2 4-nitrophenylboronic acid 
• 899445-56-8 (4-nitrobenzenesulfonylethynyl)trimethylsilane 
• 98-95-3 nitrobenzene 
• 1643-19-2 tetrabutylammomium bromide 
• 292638-85-8 acrylic acid methyl ester 
• 623-00-7 4-bromobenzenecarbonitrile 
• 15959-31-6 sodium 4-nitrobenzenesulfinate 
• 636-98-6 p-nitrobenzene iodide 
• 882-06-4 4-nitro-trans-cinnamic acid 
• 71-36-3 butan-1-ol 
• 1142-27-4 p-nitrophenyl N,N-dimethylsulphamate 

Downstream Products

• 62-23-7 4-nitro-benzoic acid 
• 86622-82-4 n-butyl 3-[4-(piperazin-1-yl)-phenyl]-propionate 

Relevant articles and documents

Pd supported on clicked cellulose-modified magnetite-graphene oxide nanocomposite for C-C coupling reactions in deep eutectic solvent

Cellulose-modified magnetite-graphene oxide nanocomposite was prepared via click reaction and utilized for immobilization of palladium (Pd) nanoparticles without using additional reducing agent. The abundant OH groups of cellulose provided the uniform dispersion and high stability of Pd nanoparticles, while magnetite-graphene oxide as a supporting material offered high specific surface area and easy magnetic separation. The as-prepared nanocomposite served as a heterogeneous catalyst for the Heck and Sonogashira coupling reactions in various hydrophilic and hydrophobic deep eutectic solvents (DESs) as sustainable and environmentally benign reaction media. Among the fifteen DESs evaluated for coupling reactions, the hydrophilic DES composed of dimethyl ammonium chloride and glycerol exhibited the best results. Due to the low miscibility of catalyst and DES in organic solvents, the separated aqueous phase containing both of the catalyst and DES can be readily recovered by evaporating water and retrieved eight times with negligible loss of catalytic performance.

Fe-MIL-101 modified by isatin-Schiff-base-Co: a heterogeneous catalyst for C-C, C-O, C-N, and C-P cross coupling reactions

A metal-organic framework functionalized with a cobalt-complex is preparedviapost-synthetic modification of Fe-MIL-101-NH2. Initially, Fe-MIL-101-NH2reacted with isatin to produce Fe-MIL-101-isatin-Schiff-base, which can anchor the cobalt by the addition of cobalt acetate. The resulting MOF-Co catalyst is characterized by employing multiple techniques. This new modified MOF acts as a heterogeneous and recyclable catalyst for efficient Ullmann, Buchwald-Hartwig, Hirao, Hiyama and Mizoroki-Heck cross-coupling reactions of several aryl halides/phenylboronic acid/phenyltosylate with phenols, anilines/heterocyclic amines, triethyl phosphite, triethoxyphenylsilane and alkenes and generates the expected coupling products in good to high yields.

A comparative study of palladium-based coordination compounds with bidentate (N,N, P,P and P,O) ligands; Design, synthesis, X-ray structural, catalytic activity and DFT studies

This account describes our recent studies on four new asymmetric cyclometallated Pd(II) complexes with a formula [L1 → Pd ← L2](ClO4) (L1 = benzylamine and L2 = bis (diphenylphosphino) methane oxide (