866458-32-4

Basic information

• Product Name: (R)-Phenyl-(2,4,6-trimethyl-benzenesulfonylamino)-acetyl chloride
• CAS NO: 866458-32-4
• Molecular Weight: 351.854
• Mol File: 866458-32-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-Phenyl-(2,4,6-trimethyl-benzenesulfonylamino)-acetyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-Phenyl-(2,4,6-trimethyl-benzenesulfonylamino)-acetyl chloride(866458-32-4)
• EPA Substance Registry System: (R)-Phenyl-(2,4,6-trimethyl-benzenesulfonylamino)-acetyl chloride(866458-32-4)

Safety Data

• Hazardous Substances Data: 866458-32-4(Hazardous Substances Data)

Upstream product

• 186801-10-5 N-(2,4,6-trimethyl-benzenesulfonyl)-D-phenylglycine 
• 773-64-8 2-mesitylenesulphonyl chloride 
• 875-74-1 (R)-phenylglycine 

Relevant articles and documents

Amino acid-derived hydroxamic acids as chiral ligands in the vanadium catalysed epoxidation

New sulfonamide-derived hydroxamic acids 7-11 have been developed as chiral ligands for the V-catalysed asymmetric epoxidation, showing high reactivity at subzero temperatures and moderate to good enantioselectivity. The strong accelerating effect exhibited by the ligands of this type can be attributed to the sulfonamide functionality. A range of cinnamyl type allylic alcohols were epoxidised with up to 74% ee. The Royal Society of Chemistry 2005.