866487-70-9

Basic information

• Product Name: 2-(2-benzyl-allyl)-isoindole-1,3-dione
• Synonyms: 2-(2-benzyl-allyl)-isoindole-1,3-dione
• CAS NO: 866487-70-9
• Molecular Weight: 277.323
• Mol File: 866487-70-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(2-benzyl-allyl)-isoindole-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-benzyl-allyl)-isoindole-1,3-dione(866487-70-9)
• EPA Substance Registry System: 2-(2-benzyl-allyl)-isoindole-1,3-dione(866487-70-9)

Safety Data

• Hazardous Substances Data: 866487-70-9(Hazardous Substances Data)

Upstream product

• 136918-14-4 phthalimide 
• 30457-89-7 2-benzylallyl alcohol 

Downstream Products

• 1447974-59-5 tert-butyl (2-benzylallyl)carbamate 
• 1447974-68-6 5-benzyl-5-(chloromethyl)oxazolidin-2-one 
• 1447974-75-5 5-benzyl-5-(chloromethyl)oxazolidin-2-one 
• 1007130-10-0 C₁₈H₁₇NO₂ 
• 866487-77-6 2-(2-methyl-3-phenyl-propyl)-isoindole-1,3-dione 

Relevant articles and documents

Rhodium-catalyzed asymmetric hydroformylation of 1,1-disubstituted allylphthalimides: A catalytic route to β3-amino acids

The high enantioselective rhodium-catalyzed hydroformylation of 1,1-disubstituted allylphthalimides has been developed. By employing chiral ligand 1,2-bis[(2S,5S)-2,5-diphenylphospholano]ethane [(S,S)-Ph-BPE], a series of β3-aminoaldehydes can be prepared with up to 95% enantioselectivity. This asymmetric procedure provides an efficient alternative route to prepare chiral β3-amino acids and alcohols. Copyright

Enantioselective hydrogenation of allylphthalimides: An efficient method for the synthesis of β-methyl chiral amines

(Chemical Equation Presented) High yields and up to 98% ee have been achieved by asymmetric hydrogenation of allylphthalimides followed by hydrolysis to give β-methyl chiral amines by using a Ru-C3-tunephos catalyst (see scheme). The synthetic utility of this procedure has been demonstrated through the synthesis of the key intermediate of the LTs receptor antagonist (Zeneca ZD 3532).