86766-60-1

Basic information

• Product Name: Carbamic acid, (1-phenyl-2-propenyl)-, methyl ester
• Synonyms: N-(1-Phenyl-allyl)-carbamidsaeure-methylester;Carbamic acid,(1-phenyl-2-propenyl)-,methyl ester
• CAS NO: 86766-60-1
• Molecular Formula: C11H13NO2
• Molecular Weight: 191.23
• Mol File: 86766-60-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 70 °C(Press: 0.008 Torr)
• Density: 1.062±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Carbamic acid, (1-phenyl-2-propenyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (1-phenyl-2-propenyl)-, methyl ester(86766-60-1)
• EPA Substance Registry System: Carbamic acid, (1-phenyl-2-propenyl)-, methyl ester(86766-60-1)

Safety Data

• Hazardous Substances Data: 86766-60-1(Hazardous Substances Data)

Upstream product

• 300-57-2 allylbenzene 
• 1027911-01-8 (2,2,2-Trichloro-acetyl)-carbamic acid (E)-3-phenyl-allyl ester 
• 1189-71-5 isocyanate de chlorosulfonyle 
• 16277-67-1 (Z)-(3-methoxyprop-1-en-1-yl)benzene 
• 24808-73-9 (E)-(3-methoxyprop-1-en-1-yl)benzene 
• 22665-13-0 1-phenylallyl methyl ether 
• 67-56-1 methanol 
• 55887-59-7 1-Phenyl-allylisocyanat 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 1078-70-2 3-phenylprop-2-enyloxycarbonylamine 

Downstream Products

• 86766-70-3 N-methyl-N-<α-phenyl-allyl>amine 
• 86766-76-9 Methyl N-(1-Phenyl-1-propenyl)carbamate 
• 4393-21-9 1-(phenyl)allylamine 

Relevant articles and documents

Study of the stability of carbocations by chlorosulfonyl isocyanate reaction with ethers

The stability order of various alkyl, allyl, and benzyl carbocations was investigated using the novel technique for comparing the stability of carbocations in solution developed by using a simple CSI reaction with various ethers. The p-methoxycinnamyl carbocation was the most stable in our reaction system and the next stable carbocation was the p-methoxybenzyl carbocation. The stability of the other carbocations decreased with methacryl, t-butyl, cinnamyl, acryl, benzyl, 2° and allyl carbocations in that order.

Novel synthetic method for N-allylcarbamates from allyl ethers using chlorosulfonyl isocyanate

Various allyl ethers were converted into the corresponding N- allylcarbamates using chlorosulfonyl isocyanate (CSI) via the stable allylic carbocation rather than β-lactam through [2+2] cycloaddition. The reaction of cinnamyl methyl ether with CSI afforded only methyl N-cinnamylcarbamate at 0°C, but at 20°C, it produced a mixture of methyl N-cinnamylcarbamate and methyl N-(l-phenylprop-2-enyl)carbamate in a 2.7:1 ratio. (C) 2000 Elsevier Science Ltd.

Bis(methoxycarbonyl)sulfur Diimide, a Convenient Reagent for the Allylic Amination of Alkenes

-