86886-42-2Relevant articles and documents
Sequential Acylation/Silylation/Hetero-Claisen Rearrangement of Nitroalkanes for the Synthesis of Protected Hydroxyoxime Derivatives
Antonova, Yulia A.,Ioffe, Sema L.,Sukhorukov, Alexey Yu.,Tabolin, Andrey A.
, p. 3197 - 3213 (2021)
Sequential acylation-silylation of nitroalkanes leads to O-silylated α-acyloxyoximes in high yields. The first step of the reaction involves deprotonation of nitro compound with sodium hydride promoted by DBU or alcohol/15-crown-5 system followed by treat