87436-97-3

Basic information

• Product Name: C₉H₁₄MgSi
• Synonyms: C₉H₁₄MgSi
• CAS NO: 87436-97-3
• Molecular Weight: 174.601
• Mol File: 87436-97-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₉H₁₄MgSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₉H₁₄MgSi(87436-97-3)
• EPA Substance Registry System: C₉H₁₄MgSi(87436-97-3)

Safety Data

• Hazardous Substances Data: 87436-97-3(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 3839-31-4 dimethyl(phenyl)silyllithium 

Downstream Products

• 104066-53-7 (E)-1-dimethylphenylsilyl-4-(2-tetrahidropyranyloxy)-1-butene 
• 91076-15-2 (Z)-1-(Dimethyl-phenyl-silanyl)-9-trimethylsilanyl-cyclononene 
• 91076-20-9 (E)-2-(Dimethyl-phenyl-silanyl)-hepta-1,5-dien-4-ol 
• 91076-16-3 3-(1-hydroxy-2-butenyl)-2-dimethylphenylsilyl-1-cyclononene 
• 91076-17-4 dimethyl(phenyl)(prop-1-en-2-yl)silane 
• 91076-24-3 2-dimethylphenylsilyl-1-tridecene 
• 108025-34-9 cyclohex-1-en-1-yldimethyl(phenyl)silane 
• 64545-10-4 (E)-(hex-1-en-1-yl)dimethyl(phenyl)silane 
• 93184-00-0 1-dimethylsilylphenylmethyl-1-cyclopentene 
• 93526-76-2 Dimethyl-[2-methyl-cycloprop-(Z)-ylidenemethyl]-phenyl-silane 
• 93526-75-1 Dimethyl-(3-methyl-cyclobut-1-enyl)-phenyl-silane 
• 79035-73-7 (E/Z)-(1-ethyl-1-propenyl)dimethylphenylsilane 
• 93131-29-4 [2-Butyl-cyclopent-(Z)-ylidenemethyl]-dimethyl-phenyl-silane 
• 91076-19-6 1-phenyl-3-(phenyldimethylsilyl)-3-buten-1-ol 

Relevant articles and documents

TRANSITION-METAL CATALYZED SILYLMETALATION OF ALLENES

Addition of PhMe2SiMgMe, (PhMe2Si)2Zn, or PhMe2SiAlEt2 to allenes proceeds in the presence of various transition-metal catalysts.Whereas copper catalyzed silylmagnesation of 1,2-cyclononadiene gives 1-dimethyl-phenylsilyl-1-cyclononene exclusively, palladium catalyzed silylalumination affords 3-dimethylphenylsilyl-1-cyclononene preferentially with high degrees of regioselectivity.