87591-35-3

Basic information

• Product Name: METHYL 2,3,4-TRI-O-ACETYL-6-O-TRIPHENYLMETHYL-BETA-D-GALACTOPYRANOSIDE
• Synonyms: METHYL TRI-O-ACETYL-6-O-TRITYL-BETA-D-GALACTOPYRANOSIDE;METHYL 2,3,4-TRI-O-ACETYL-6-O-TRIPHENYLMETHYL-BETA-D-GALACTOPYRANOSIDE;METHYL TRI-O-ACETYL-6-O-TRITYL-SS-D-GALACTOPYRANOSIDE
• CAS NO: 87591-35-3
• Molecular Formula: C₃₂H₃₄O₉
• Molecular Weight: 562.61
• Mol File: 87591-35-3.mol
• Article Data: 15

Chemical Properties

• Appearance: /
• CAS DataBase Reference: METHYL 2,3,4-TRI-O-ACETYL-6-O-TRIPHENYLMETHYL-BETA-D-GALACTOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 2,3,4-TRI-O-ACETYL-6-O-TRIPHENYLMETHYL-BETA-D-GALACTOPYRANOSIDE(87591-35-3)
• EPA Substance Registry System: METHYL 2,3,4-TRI-O-ACETYL-6-O-TRIPHENYLMETHYL-BETA-D-GALACTOPYRANOSIDE(87591-35-3)

Safety Data

• Hazardous Substances Data: 87591-35-3(Hazardous Substances Data)

Upstream product

• 76-83-5 trityl chloride 
• 108-24-7 acetic anhydride 
• 18311-26-7 methyl 6-O-trityl-α-D-glucopyranoside 
• 29411-57-2 methyl-α-D-altropyranoside 
• 604-70-6 Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-methoxy-tetrahydro-pyran-4-yl ester 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 3458-28-4 D-Mannose 
• 20231-36-1 methyl 6-O-trityl-α-D-mannopyranoside 
• 596-43-0 bromo-triphenyl-methane 
• 1824-94-8 methyl beta-D-galactopyranoside 
• 18311-26-7 methyl 6-O-triphenylmethyl-β-D-galactopyranoside 

Downstream Products

• 18031-51-1 methyl 2,3,6-tri-O-acetyl-α-D-glucopyranoside 
• 7432-72-6 methyl 2,3,4-tri-O-acetyl-α-D-glucopyranose 
• 1372204-42-6 methyl 6-deoxy-6-(4-(5-trifluoromethyl-2(1H)-pyridone-1-yl)-anilino)-α-D-mannopyranoside 
• 1372204-43-7 methyl 6-deoxy-6-(3-chloro-4-(5-trifluoromethyl-2(1H)-pyridone-1-yl)-anilino)-α-D-mannopyranoside 
• 1372204-44-8 methyl 6-deoxy-6-(3-(5-trifluoromethyl-2(1H)-pyridone-1-yl-methyl)-anilino)-α-D-mannopyranoside 
• 1372204-41-5 methyl 6-deoxy-6-(2-(5-trifluoromethyl-2(1H)-pyridone-1-yl-methyl)-anilino)-α-D-glucopyranoside 
• 1372204-33-5 methyl 6-deoxy-6-(4-(5-trifluoromethyl-2(1H)-pyridone-1-yl)-anilino)-α-D-glucopyranoside 
• 1372204-35-7 methyl 6-deoxy-6-(3-chloro-4-(5-trifluoromethyl-2(1H)-pyridone-1-yl)-anilino)-α-D-glucopyranoside 
• 1372204-37-9 methyl 6-deoxy-6-(3-(5-trifluoromethyl-2(1H)-pyridone-1-yl-methyl)-anilino)-α-D-glucopyranoside 

Relevant articles and documents

Visible-Light-Mediated, Chemo- and Stereoselective Radical Process for the Synthesis of C-Glycoamino Acids

An approach for efficient synthesis of C-glycosyl amino acids is described. Different from typical photoredox-catalyzed reactions of imines, the new process follows a pathway in which α-imino esters serve as electrophiles in chemoselective addition reactions with nucleophilic glycosyl radicals. The process is highlighted by the mild nature of the reaction conditions, the highly stereoselectivity attending C-C bond formation, and its applicability to C-glycosylations using both armed and disarmed pentose and hexose derivatives.

Diazepinium perchlorate: a neutral catalyst for mild, solvent-free acetylation of carbohydrates and other substances

Diazepinium perchlorate, an essentially neutral organic salt possessing excellent stability, has been found to be well suited for the acetylation of free as well as partially protected sugars, phenols, thiophenols, thiols and other alcohols as well as amines. The diazepinium perchlorate-catalyzed acetylation is mild, organic and solvent-free and leaves acid sensitive protecting groups such as TBDMS/TBDPS/Tr ethers and isopropylidene/benzylidene acetals present on a substrate unaffected. Regioselective hydroxyl protection in partially protected carbohydrate derivatives/polyhydroxylic compounds was possible and was proved to be a convenient time-saving alternative to the conventional synthesis of such compounds. Easy preparation of the catalyst, mild reaction conditions and an environmentally benign protocol are some of the notable features of this reaction. The results obtained on the acetylation of phenols and thiophenols could be rationalized through their local nucleophilicity index obtained from DFT calculations.

Design, synthesis and antifibrotic activities of carbohydrate-modified 1-(substituted aryl)-5-trifluoromethyl-2(1H) pyridones

Pirfenidone, a pyridone compound, is an effective and novel antifibrotic agent. In this article, we describe the design, synthesis and activity evaluation of novel antifibrotic agents, 1-(substituted aryl)-5-trifluoromethyl- 2(1H) pyridones modified with