87797-12-4

Basic information

• Product Name: 1-methoxy-4-(4-(p-methoxyphenyl)but-3-enyl)benzene
• Synonyms: 1-methoxy-4-(4-(p-methoxyphenyl)but-3-enyl)benzene
• CAS NO: 87797-12-4
• Molecular Weight: 268.356
• Mol File: 87797-12-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-methoxy-4-(4-(p-methoxyphenyl)but-3-enyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-4-(4-(p-methoxyphenyl)but-3-enyl)benzene(87797-12-4)
• EPA Substance Registry System: 1-methoxy-4-(4-(p-methoxyphenyl)but-3-enyl)benzene(87797-12-4)

Safety Data

• Hazardous Substances Data: 87797-12-4(Hazardous Substances Data)

Upstream product

• 35191-43-6 1-(4-bromo-butyl)-4-methoxy-benzene 
• 52244-70-9 4-(4-methoxyphenyl)butan-1-ol 
• 935-50-2 4,4-dimethoxycyclohexa-2,5-dienone 
• 87797-15-7 4-(4-methoxyphenyl)butyl triphenylphosphonium bromide 
• 637-69-4 4-Methoxystyrene 
• 140-67-0 Estragole 
• 20401-88-1 3-(4-methoxyphenyl)propional 
• 1530-38-7 ((4-methoxyphenyl)methyl)triphenylphosphonium bromide 
• 150-76-5 4-methoxy-phenol 
• 100-66-3 methoxybenzene 
• 81786-51-8 1-methanesulfonyloxy-4-(4-methoxyphenyl)butane 
• 4521-28-2 4-(4-Methoxyphenyl)butyric acid 
• 87797-18-0 1-[4-(4,4-Dimethoxy-cyclohexa-2,5-dienylidene)-butyl]-4-methoxy-benzene 

Downstream Products

• 1191292-48-4 N-[7-methoxy-1-(4-methoxyphenyl)-1,2,3,4-tetrahydronaphthalen-2-yl]-4-nitrobenzenesulfonamide 

Relevant articles and documents

A one-pot stereoselective synthesis of trans-1-aryl-2-aminotetralins from 2-arylethyl styrenes

An efficient stereoselective synthesis of trans-1-aryl-2-aminotetralins has been achieved via Cu(OTf)2 catalyzed one-pot aziridination and regioselective intramolecular arylation of in situ generated aziridines from 2-arylethyl styrenes and PhINSO2(4-NO2C6H4) [PhINNs]. Reaction of a mixture of E/Z-styrenes (≤85:15) provided trans-N-protected-1-aryl-2-aminotetralins with high diastereoselectivity (dr > 95:5), which are important synthons for many artificial pharmaceuticals.

Isomerization during olefin metathesis: An assessment of potential catalyst culprits

Two ruthenium hydride complexes commonly proposed as agents of unintended isomerization during olefin metathesis are examined for their activity in isomerization of estragole, a representative allylbenzene. Neither proves kinetically competent to account for the levels of isomerization observed during cross-metathesis of estragole by the second-generation Grubbs catalyst. A structure-activity analysis of selected ruthenium hydride complexes indicates that higher isomerization activity correlates with a more electrophilic metal center. It wasn't me: Two Ru hydrides thought to trigger double-bond migration during olefin metathesis are examined for their isomerization activity. Neither can account for the high levels of undesired isomerization seen during self-metathesis of estragole, a model allylbenzene substrate. Higher activity is found to correlate with a less electron-rich Ru center. Copyright

Highly selective dimerization of styrenes and linear co-dimerization of styrenes with ethylene catalyzed by a ruthenium complex

(Chemical Equation Presented) Heads you win: An unusual head-to-head dimerization of styrenes has been developed using the zero-valent ruthenium catalyst [Ru(η6-cot)(η2-dmfm)2] (cot = 1,3,5-cyclooctatriene, dmfm = dimethyl fumarate) in the presence of primary alcohols to give the homo-dimer in high regio- and stereoselectivity. The catalyst system is also effective for the selective co-dimerization of styrenes with ethylene to give the co-dimer in high yield.