87947-46-4

Basic information

• Product Name: (1S,3S,4R)-2-(4-Chloro-benzenesulfonyl)-3-trichloromethyl-2-aza-bicyclo[2.2.1]hept-5-ene
• CAS NO: 87947-46-4
• Molecular Weight: 387.114
• Mol File: 87947-46-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,3S,4R)-2-(4-Chloro-benzenesulfonyl)-3-trichloromethyl-2-aza-bicyclo[2.2.1]hept-5-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,3S,4R)-2-(4-Chloro-benzenesulfonyl)-3-trichloromethyl-2-aza-bicyclo[2.2.1]hept-5-ene(87947-46-4)
• EPA Substance Registry System: (1S,3S,4R)-2-(4-Chloro-benzenesulfonyl)-3-trichloromethyl-2-aza-bicyclo[2.2.1]hept-5-ene(87947-46-4)

Safety Data

• Hazardous Substances Data: 87947-46-4(Hazardous Substances Data)

Upstream product

• 81924-15-4 N-(2,2,2-trichloroethylidene)-4-chlorobenzenesulfonamide 
• 542-92-7 cyclopenta-1,3-diene 
• 17260-65-0 N,N-dichloro-4-chlorobenzenesulfonamide 

Relevant articles and documents

Diels–Alder trapping vs. amidoalkylation of cyclopentadiene with polychloroacetaldehyde sulfonylimines

The reaction of chloral or dichloro(phenyl)acetaldehyde N-arylsulfonylimines with cyclopentadiene, depending on the reaction conditions, affords either Diels–Alder adducts, 2-arylsulfonyl-2-azabicyclo[2.2.1]hept-5-enes, or unexpectedly new amidoalkylated

SINGLE-STAGE SYNTHESIS OF N-ARYLSULFONYL-SUBSTITUTED 1,2,3,6-TETRAHYDROPYRIDINES AND 2-AZABICYCLOHEPT-5-ENES

The reaction of trichloroethylidenearenesulfonamides with the formula CCl3CH=NSO2C6H4X (X=H, Cl, CH3), obtained in a single stage from trichloroethylene and N,N-dichloroarenesulfonamides, with piperylene and isoprene leads to N-arylsulfonyl-2-trichloromet