88382-05-2

Basic information

• Product Name: Benzenemethanamine, N-hydroxy-a-2-propenyl-
• CAS NO: 88382-05-2
• Molecular Formula: C10H13NO
• Molecular Weight: 163.219
• Mol File: 88382-05-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-hydroxy-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-hydroxy-a-2-propenyl-(88382-05-2)
• EPA Substance Registry System: Benzenemethanamine, N-hydroxy-a-2-propenyl-(88382-05-2)

Safety Data

• Hazardous Substances Data: 88382-05-2(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 51851-79-7 diisopropyl allylboronate 
• 932-90-1 Benzaldoxime 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1594-94-1 allyl dimethyl boronic acid ester 

Downstream Products

• 4383-23-7 1-phenyl-but-3-enylamine 
• 76897-07-9 1-phenylbut-3-en-1-amine hydrochloride 
• 88382-06-3 N-Benzyliden-N-(1-phenyl-3-butenyl)amin-N-oxid 
• 102652-41-5 C₁₄H₁₉NO 

Relevant articles and documents

Arylboronic Acid-Catalyzed C-Allylation of Unprotected Oximes: Total Synthesis of N-Me-Euphococcine

O-Unprotected keto-and aldoximes are readily C-allylated with allyl diisopropyl boronate in the presence of arylboronic acid catalysts to yield highly substituted N-α-secondary and tertiary homoallylic hydroxylamines. The method was used in the total synthesis of the trace alkaloid N-Me-Euphococcine.

Addition of Allylboronates to Schiff Bases and to Oximes

Clean addition of allylboronates of Type 3 to Schiff bases 2 leads to the secondary homoallylamines 4.Analogous addition to the oximes 9 results in the formation of the hydroxylamines 13.The latter allow the generation of the primary homoallylamines 14.