88639-56-9

Basic information

• Product Name: Heptane, 1,1,1-trichloro-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-
• CAS NO: 88639-56-9
• Molecular Formula: C7Cl3F13
• Molecular Weight: 437.415
• Mol File: 88639-56-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Heptane, 1,1,1-trichloro-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Heptane, 1,1,1-trichloro-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-(88639-56-9)
• EPA Substance Registry System: Heptane, 1,1,1-trichloro-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-(88639-56-9)

Safety Data

• Hazardous Substances Data: 88639-56-9(Hazardous Substances Data)

Upstream product

• 66443-85-4 perfluoro-2-octanone 

Relevant articles and documents

REACTION OF PHOSPHORUS PENTACHLORIDE WITH PERHALO CARBONYL-CONTAINING COMPOUNDS

The reaction between PCl5 and the carbonyl oxygen in a variety of perfluoro compounds containing the carbonyl functional group, e.g.RfC(O)R'f, RfC(O)X or XC(O)RfC(O)X, where X = Cl, F, OH, NH2, and ONH4 has led to a convenient synthesis procedure for fluorochlorocompounds.Monoketones, e.g.RfC(O)R'f, yield RfCCl2R'f compounds, while the diketones, e.g.RfC(O)(CF2)nC(O)R'f, also react to yield the fluorochloro compounds.When n = 3, RfCCl2(CF2)3CCl2R'f is produced in quite high yields (65 percent); however, when n = 2, the principal product is a cyclic fluorodichloroether compound while the fluorotetrachloro compound is the minor product.The RfC(O)X and XC(O)RfC(O)X compounds produce RfCCl3 and Cl3CRfCCl3 respectively in high yields.Reaction temperature and pressure are important factors for high yield synthesis.