88708-61-6Relevant articles and documents
Synthesis of β-hydroxyphosphonates by iron-catalyzed oxidative addition of phosphonyl radicals to alkenes
Taniguchi, Tsuyoshi,Idota, Atsushi,Yokoyama, Shin'Ichi,Ishibashi, Hiroyuki
experimental part, p. 4768 - 4770 (2011/10/02)
Phosphorohydrazidates have been shown to work as radical precursors by iron-catalyzed aerobic oxidation to generate corresponding phosphonyl radicals. Generated radicals cause intermolecular addition to various alkenes in the presence of molecular oxygen
FLUORIDE ION INDUCED TERMINAL OLEFIN SYNTHESIS FROM β-HYDROXYALKYLPHOSPHONATES
Kawashima, Takayuki,Ishii, Takafumi,Inamoto, Naoki
, p. 1375 - 1378 (2007/10/02)
β-Hydroxyalkylphosphonates, prepared readily from alkylphosphonates and carbonyl compounds, were treated with a fluoride ion to give the corresponding olefins in fairly good yields.Use of CsF in N,N-dimethylformamide gave the best result.