888041-37-0Relevant articles and documents
Synthetic method of 2,7-dibromo-benzo[9,10]phenanthrene
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, (2019/05/02)
The invention belongs to the technical field of organic chemical synthesis, and relates to a synthetic method of triphenylene, in particular to a synthetic method of 2,7-dibromo-benzo[9,10]phenanthrene. The synthetic method includes dissolving 4,4'-dibromobiphenyl in dichloromethane; adopting a mixed solution of nitric acid and sulfuric acid for nitration reaction, and carrying out washing, concentrating and recrystallizing to obtain 2-nitro-4,4'-dibromobiphenyl, wherein the yield is 82%; reducing a nitro group into an amino group by a Fe/NH4Cl system, and subjecting the obtained product and benzene to diazo coupling reaction to obtain 4,4'-dibromo-1,1',2',1-terphenyl; performing oxidative coupling by a Pd/trifluoromethanesulfonic acid system to obtain the 2,7-dibromo-benzo[9,10]phenanthrene, wherein the yield is 62.5%, and the HPCL purity is 99.5%. The synthetic method avoids the problems of complex synthesis, low yield and environmental pollution in conventional methods.
COMPOUND CONTAINING SUBSTITUTED TRIPHENYLE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
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, (2014/01/17)
An organic compound having an excellent electron injection and transport performance is provided as a material for a low-power-consumption organic electroluminescent device. A low-power-consumption organic electroluminescent device is also provided by using the compound. The compound is a compound of general formula (1) or (2) having a substituted bipyridyl and triphenylene ring structure. The organic electroluminescent device includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes, and uses the compound as constituent material of at least one of the organic layers.