88920-84-7

Basic information

• Product Name: Benzene, (4,4-dichloro-3-butenyl)-
• CAS NO: 88920-84-7
• Molecular Formula: C10H10Cl2
• Molecular Weight: 201.095
• Mol File: 88920-84-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, (4,4-dichloro-3-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4,4-dichloro-3-butenyl)-(88920-84-7)
• EPA Substance Registry System: Benzene, (4,4-dichloro-3-butenyl)-(88920-84-7)

Safety Data

• Hazardous Substances Data: 88920-84-7(Hazardous Substances Data)

Upstream product

• 2233-00-3 3,3,3-trichloro-1-propene 
• 108-88-3 toluene 
• 124-19-6 nonan-1-al 
• 358720-79-3 acetic acid 3-phenyl-1-trichloromethyl-propyl ester 
• 358720-84-0 trimethyl(1,1,1-trichloro-4-phenylbutan-2-yloxy)silane 
• 119405-97-9 4-phenyl-1,1-dibromo-1-butene 
• 104-53-0 3-phenyl-propionaldehyde 
• 75-62-7 Bromotrichloromethane 
• 82772-38-1 α-(trichloromethyl)benzenepropanol 
• 650-51-1 sodium trichloroacetate 
• 56-23-5 tetrachloromethane 
• 88920-82-5 1,1-Dichloro-4-phenyl-1-trimethylsilanyl-butan-2-ol 

Downstream Products

• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 103240-58-0 2,6-diphenylhexa-2,3-diene 
• 76181-40-3 1-chloro-3,4-dihydronaphthalene 
• 16520-62-0 4-Phenyl-1-butyne 

Relevant articles and documents

A Robust One-Step Approach to Ynamides

A robust one-step synthetic strategy for ynamide with cheap and easily available stock chemicals vinyl dichlorides and electron deficient amides as the starting material is described. In the absence of transition-metal catalyst, the reaction proceeds under mild reaction conditions in open air and thus rendering a convenient operation. This strategy is not only suitable for both terminal and internal ynamide synthesis but also amenable for large-scale preparation. Broad substrate scopes with respect to vinyl dichloride as well as electron-deficient amide were observed.

The use of bromotrichloromethane in chlorination reactions

Carbon tetrachloride is no longer used as a common solvent due to its toxicity and harmful environmental impact. The synthesis of gem-dichloroalkenes from aldehydes by using triphenylphosphine typically requires carbon tetrachloride as a solvent. We report that stoichiometric bromotrichloromethane in acetonitrile can be used in place of solvent quantities of carbon tetrachloride in this transformation. Similarly, bromotrichloromethane in dichloromethane can be used for the room-temperature Appel reaction of benzyl alcohols to form benzyl chlorides, which is commonly carried out in refluxing carbon tetrachloride. Georg Thieme Verlag Stuttgart New York.

Novel ambiphilic dichlorocarbenoid equivalent in alkene cyclopropanation and carbonyl olefination

The Ti-Mg-dichloromethylene complexes derived from the oxidative addition of CCl4 to the Mg-TiCl4 bimetallic species serve as a novel class of ambiphilic dichlorocarbenoid equivalents. Not only is Ti-Mg-dichlorocarbenoid highly selective but also it seems highly reactive in both alkene cyclopropanations and carbonyl dichloromethylenations.