89025-53-6

Basic information

• Product Name: Pyridine, 2-(pentadecylthio)-
• CAS NO: 89025-53-6
• Molecular Formula: C20H35NS
• Molecular Weight: 321.571
• Mol File: 89025-53-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-(pentadecylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-(pentadecylthio)-(89025-53-6)
• EPA Substance Registry System: Pyridine, 2-(pentadecylthio)-(89025-53-6)

Safety Data

• Hazardous Substances Data: 89025-53-6(Hazardous Substances Data)

Upstream product

• 56-23-5 tetrachloromethane 
• 89025-67-2 N-palmitoxy-2-pyridinethione 
• 1121-30-8 1-hydroxy-2(1H)-pyridinethione 
• 37850-75-2 allyl tert-butyl sulfide 
• 112-67-4 n-hexadecanoyl chloride 
• 76126-87-9 3-(2,4,6-trimethylphenylthio)prop-1-ene 
• 108055-32-9 allyl 2-methylene-3-t-butylthiopropanoate 
• 3811-73-2 2-mercaptopyridine-1-oxide sodium salt 
• 14370-82-2 allyl phenyl selenide 
• 32894-70-5 allyl 4-nitrophenyl sulfide 
• 3112-87-6 1-methyl-4-(prop-2-ene-1-sulfonyl)benzene 
• 5296-64-0 allyl phenyl thioether 

Relevant articles and documents

Quantum Yields in the Photochemically Induced Radical Chemistry of Acyl Derivatives of Thiohydroxamic Acids

Acyl derivatives of N-hydroxyquinazoline-4-thiones are a novel source of disciplined carbon radicals.Quantum yield determination reveals that photolysis of these compounds initiates radical chains, resulting in quantum yields up to φ = 60.Comparative studies with acyl derivatives of N-hydroxy-2-thiopyridone show that the quinazoline derivatives are more light-sensitive than the thiopyridone compounds.The carbon radicals thus formed from the former can be trapped selectively, without the formation of rearranged products (i.e. without the competition of the radicophilic thiocarbonyl group of the starting material with the radical trap).

LIGHT INDUCED HALOGENATIVE DECARBOXYLATION OF THIOHYDROXAMIC ESTERS

The generality of lidht initiated halogenative decarboxylation of thiohydroxamic esters was studied.This method gave high yields of alkyl chlorides, bromides and iodides derived from primary, secondary and tertiairy substituted carboxylic acids.

The Invention of New Radical Chain Reactions. Part 12. Improved Methods for the Addition of Carbon Radicals to Substituted Allylic Groups

Reagents for the allylation of carbon radicals derived from the esters (mixed anhydrides) of N-hydroxy-2-thiopyridone have been investigated.Because of competition between the background reaction of decarboxylative rearrangement and the desired allylation process, conventional allylation reagents give moderate yields of the desired adducts.Improved yields are secured if the β-position bears an electron withdrawing group.A concerted addition and elimination process can be postulated.