89224-95-3

Basic information

• Product Name: Benzoic acid, 5-methoxy-2-(phenylamino)-
• Synonyms: 2-Anilino-5-methoxy-benzoesaeure;4-Methoxy-diphenylamin-carbonsaeure-(2);Benzoic acid,5-methoxy-2-(phenylamino);2-anilino-5-methoxy-benzoic acid;5-methoxy-2-(phenylamino)benzoic acid;5-methoxy-N-phenylanthranilic acid
• CAS NO: 89224-95-3
• Molecular Formula: C14H13NO3
• Molecular Weight: 243.262
• Mol File: 89224-95-3.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 5-methoxy-2-(phenylamino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 5-methoxy-2-(phenylamino)-(89224-95-3)
• EPA Substance Registry System: Benzoic acid, 5-methoxy-2-(phenylamino)-(89224-95-3)

Safety Data

• Hazardous Substances Data: 89224-95-3(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 54413-93-3 2-iodo-5-methoxybenzoic acid 
• 95216-58-3 potassium 2-chloro-5-methoxybenzoate 
• 22921-68-2 2-bromo-5-methoxy-benzoic acid 
• 6280-89-3 2-chloro-5-methoxybenzoic acid 

Downstream Products

• 89224-76-0 6-methoxy-1-phenyl-1,2-dihydro-(4H)-3,1-benzoxazin-4-one 
• 1428865-12-6 C₁₆H₁₇NO₃ 
• 1428865-25-1 C₁₅H₁₇NO₂ 
• 1428865-37-5 5-methoxy-2-(methyl(phenyl)amino)benzaldehyde 
• 16492-13-0 9-chloro-2-methoxyacridine 
• 89224-79-3 5-methoxy-2-<(2-methoxy-2-oxoethyl)phenylamino>benzoic acid methyl ester 
• 89224-54-4 3,7-dimethoxy-4-phenyl-4H-furo<3,2-b>indole-2-carboxylic acid methyl ester 
• 89224-52-2 5-methoxy-3-(2-methoxy-2-oxoethoxy)-1-phenyl-1H-indole-2-carboxylic acid methyl ester 
• 89224-55-5 3,7-dimethoxy-4-phenyl-4H-furo<3,2-b>indole-2-carboxylic acid 
• 89224-73-7 3,7-dimethoxy-4-phenyl-4H-furo<3,2-b>indole-2-carboxamide 
• 93424-86-3 3,4-dihydro-7-methoxy-2-methyl-3-oxo-4-phenyl-2H-furo<3,2-b>indole-2-carboxylic acid methyl ester 
• 93424-83-0 3-hydroxy-7-methoxy-4-phenyl-4H-furo<3,2-b>indole-2-carboxylic acid methyl ester 
• 89224-77-1 2-[(Cyanomethyl)phenylamino]-5-methoxy-benzoic acid 
• 89224-78-2 2-<(carboxymethyl)phenylamino>-5-methoxybenzoic acid 

Relevant articles and documents

Acid-catalyzed oxidative cross-coupling of acridans with silyl diazoenolates and a Rh-catalyzed rearrangement: two-step synthesis of γ-(9-acridanylidene)-β-keto esters

A MsOH-catalyzed oxidative cross-coupling of acridans and silyl diazoenolates and a Rh2(OAc)4-catalyzed rearrangement of the resultant diazo products are described. The reactions provide various γ-(9-acridanylidene)-β-keto esters in good yields, which bear an active α-methylene unit for further functionalization.

Redox-neutral decarboxylative photocyclization of anthranilic acids

A mild metal-, catalyst-, and oxidant-free photoredox neutral system has been found to efficiently enable intramolecular decarboxylative cyclization of anthranilic acids. This facile protocol provides an alternative method for the synthesis of carbazoles. Mechanistic studies reveal a key photoinduced 6π-electrocyclization process and formic acid was released as the sole byproduct.

PhI(OAc)2-mediated intramolecular oxidative aryl-aldehyde C sp 2-C sp 2 bond formation: Metal-free synthesis of acridone derivatives

A metal-free protocol for direct aryl-aldehyde Csp2-Csp 2 bond formation via a PhI(OAc)2-mediated intramolecular cross-dehydrogenative coupling (CDC) of various 2-(N-arylamino)aldehydes was developed. The novel methodology requires no need of preactivation of the aldehyde group, is applicable to a large variety of functionalized substrates, and most of all provides a convenient approach to the construction of biologically important acridone derivatives.