89286-44-2

Basic information

• Product Name: [Re(CO)3(P(C₆H₅)3)(C₆H₅NC(CH₃)NC₆H₅)]
• CAS NO: 89286-44-2
• Molecular Weight: 741.8
• Mol File: 89286-44-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Re(CO)3(P(C₆H₅)3)(C₆H₅NC(CH₃)NC₆H₅)](CAS DataBase Reference)
• NIST Chemistry Reference: [Re(CO)3(P(C₆H₅)3)(C₆H₅NC(CH₃)NC₆H₅)](89286-44-2)
• EPA Substance Registry System: [Re(CO)3(P(C₆H₅)3)(C₆H₅NC(CH₃)NC₆H₅)](89286-44-2)

Safety Data

• Hazardous Substances Data: 89286-44-2(Hazardous Substances Data)

Upstream product

• 14841-07-7 Re(CO)4(P(C₆H₅)3)Br 
• 621-09-0 N,N'-diphenylacetamidine 
• 90523-09-4 (Re(CO)4(CON(Ph)C(Me)NPh)) 

Relevant articles and documents

RHENIUM CARBONYL COMPLEXES. SYNTHESIS AND CHARACTERISATION OF NN'-DIARYLAMIDINES, R'NHC(R)NR' (R=H, Me, or Ph, R'=Ph or C6H4Me-p), AND RELATED CARBAMOYL DERIVATIVES

NN'-Diarylacetamidines R'NHC(Me)NR', NN'-diarylbenzamidines R'NHC(Ph)NR', and NN'-diarylformamidines R'NHC(H)NR' (R'=Ph or C6H4Me-p) react thermally or photolytically with and/or 2> (X= Cl or Br) to afford air-stable, white complexes, X>, containing monodentate amidine ligands.The corresponding lithioamidines (R= Me or Ph) gave white carbamoyl complexes >, which are converted thermally to NN'-bidentate > and ortho-metallated > (R''=H or Me).The latter complexes are also formed by further reaction of the carbamoyl complexes with the corresponding amidine.The carbamoyl complexes react with PPh3 to form >.Lithioamidines in excess react with (X= Cl or Br) complexes to give adducts formulated as Li(1+)2>(1-).The new complexes are characterised, and structural data obtained by i.r. and n.m.r. spectroscopy.