89292-23-9

Basic information

• Product Name: Benzenecarboximidoyl chloride, N-[3-(trifluoromethyl)phenyl]-
• CAS NO: 89292-23-9
• Molecular Formula: C14H9ClF3N
• Molecular Weight: 283.68
• Mol File: 89292-23-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidoyl chloride, N-[3-(trifluoromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidoyl chloride, N-[3-(trifluoromethyl)phenyl]-(89292-23-9)
• EPA Substance Registry System: Benzenecarboximidoyl chloride, N-[3-(trifluoromethyl)phenyl]-(89292-23-9)

Safety Data

• Hazardous Substances Data: 89292-23-9(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 98-16-8 3-trifluoromethylaniline 
• 1939-24-8 N-[(3-trifluoromethyl)phenyl]benzamide 

Downstream Products

• 79508-05-7 5-Methyl-1-{phenyl-[(Z)-3-trifluoromethyl-phenylimino]-methyl}-1H-pyrazole-3-carboxylic acid methyl ester 
• 425366-08-1 N-(3-trifluoromethyl-phenyl)-benzimidic acid 4-cyano-phenyl ester 
• 425366-21-8 phenylmethylidyne-(3-trifluoromethyl-phenyl)-ammonium 
• 1939-24-8 N-[(3-trifluoromethyl)phenyl]benzamide 
• 105673-74-3 N-(3-Trifluoromethyl-phenyl)-benzimidic acid 4-nitro-phenyl ester 
• 31118-27-1 N-{4-[2-(Methyl-phenyl-amino)-ethoxy]-phenyl}-N'-(3-trifluoromethyl-phenyl)-benzamidine 

Relevant articles and documents

α-Imino Iridium Carbenes from Imidoyl Sulfoxonium Ylides: Application in the One-Step Synthesis of Indoles

Imidoyl sulfoxonium ylides are presented for the first time as potential precursors to generate α-imino metal-carbene intermediates and applied in direct C-H functionalization reactions catalyzed by [Ir(cod)Cl]2 (4 mol %) to provide 2-substituted indoles (up to 70% yield) in just one step. This class of sulfur ylide is successfully obtained from imidoyl chloride and dimethylsulfoxonium methylide (23 new examples in 45-85% yield) or by imino group formation from the corresponding β-keto sulfoxonium ylides and anilines in the presence of TiCl4 as a Lewis acid (9 examples in 33-94% yield).