89604-36-4

Basic information

• Product Name: Ethanone, 1-[3-chloro-2-(methylthio)phenyl]-
• CAS NO: 89604-36-4
• Molecular Formula: C9H9ClOS
• Molecular Weight: 200.689
• Mol File: 89604-36-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[3-chloro-2-(methylthio)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[3-chloro-2-(methylthio)phenyl]-(89604-36-4)
• EPA Substance Registry System: Ethanone, 1-[3-chloro-2-(methylthio)phenyl]-(89604-36-4)

Safety Data

• Hazardous Substances Data: 89604-36-4(Hazardous Substances Data)

Upstream product

• 89587-47-3 3-Chloro-N-(2-dimethylamino-ethyl)-N-methyl-benzamide 
• 24167-52-0 N,N-dimethyl-3-chlorobenzamide 
• 535-80-8 3-chlorobenzoate 
• 147460-61-5 3-Chloro-2-methylsulfanyl-benzoyl chloride 
• 147460-60-4 3-chloro-2-(methylsufanyl)benzoic acid 
• 35227-78-2 diethyl (ethoxymagnesio)malonate 
• 624-92-0 Dimethyldisulphide 

Downstream Products

• 174785-92-3 3(5)-<3'-chloro-2'-methylthiophenyl>pyrazole 

Relevant articles and documents

Lithiations directed by carboxylic acid, fluorine and chlorine: The regioselective synthesis of polysubstituted benzoic acids and acetophenones

Lithiation/electrophilic quenching of ortho-lithiated benzoates allows the totally regiocontrolled synthesis of a wide range of 2,3-, 2,3,4-, and 2,3,4,5-polysubstituted benzoic acids and related acetophenones. Elsevier,.

ORTHO METALATION DIRECTED BY α-AMINO ALKOXIDES. AN IMPROVED SYNTHESIS OF ORTHO-SUBSTITUTED ARYL KETONES

Ortho-substituted aryl ketones are prepared from N--N-methylbenzamides via ortho lithiation of intermediate α-amino alkoxides, formed in situ by addition of RLi.An ortho lithiation of N--N-methylbenzamide is also described.