89922-59-8Relevant articles and documents
Photoactivated novel organic small-molecular matrixes and preparation method thereof, and application of photoactivated novel organic small-molecular matrixes in MALDI mass spectrometric detection
-
Paragraph 0037; 0096-0099, (2021/04/10)
The invention provides photoactivated novel organic small-molecular matrixes and a preparation method thereof, and application of the photoactivated novel organic small-molecular matrixes in MALDI mass spectrometric detection. According to the invention,
Conjugated microporous polymer based on phenothiazine, preparation method and efficient catalytic application
-
Paragraph 0039; 0044-0046, (2019/07/10)
The invention discloses a conjugated microporous polymer based on phenothiazine, a preparation method and an efficient catalytic application and belongs to the technical field of photocatalytic functional material preparation. The conjugated microporous polymer based on carbazole-phenothiazine has a high specific surface area, excellent heat stability and chemical stability and good ultraviolet absorption, has good photocatalytic activity, and can catalyze aerobic selenylation of indole efficiently in an illuminating aerobic condition. The conversion ratio is greater than 99%. As a heterogeneous catalyst, the polymer is separated and recovered conveniently and can be recycled. The conjugated microporous polymer based on phenothiazine expands the application of CMPs in photocatalysis and has important application value and application prospect.
Highly efficient phenothiazine 5,5-dioxide-based hole transport materials for planar perovskite solar cells with a PCE exceeding 20%
Ding, Xingdong,Chen, Cheng,Sun, Linghao,Li, Hongping,Chen, Hong,Su, Jie,Li, Huaming,Li, Henan,Xu, Li,Cheng, Ming
supporting information, p. 9510 - 9516 (2019/04/25)
Two novel phenothiazine 5,5-dioxide (PDO) core building block-based hole transport materials (HTMs), termed PDO1 and PDO2, were designed and synthesized. The introduction of a sulfuryl group in a core unit can deeply influence the energy levels and charge carrier mobilities of relative HTMs. The combined suitable energy level alignment, higher hole mobility and conductivity, as well as highly efficient hole transfer of PDO2 enable the perovskite solar cell (PSC) to achieve an impressive power conversion efficiency (PCE) of 20.2% and good stability when aged under ambient conditions. These results demonstrate the potential versatility of the PDO building block for further development of cost-effective and highly efficient HTMs for PSCs.