89958-53-2

Basic information

• Product Name: Mn(C₅H₄CH₃)(CH₂CHCH₂Si(C₆H₅)3)(CO)2
• Synonyms: Mn(C₅H₄CH₃)(CH₂CHCH₂Si(C₆H₅)3)(CO)2
• CAS NO: 89958-53-2
• Molecular Weight: 490.556
• Mol File: 89958-53-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mn(C₅H₄CH₃)(CH₂CHCH₂Si(C₆H₅)3)(CO)2(CAS DataBase Reference)
• NIST Chemistry Reference: Mn(C₅H₄CH₃)(CH₂CHCH₂Si(C₆H₅)3)(CO)2(89958-53-2)
• EPA Substance Registry System: Mn(C₅H₄CH₃)(CH₂CHCH₂Si(C₆H₅)3)(CO)2(89958-53-2)

Safety Data

• Hazardous Substances Data: 89958-53-2(Hazardous Substances Data)

Upstream product

• 18752-21-1 allyltriphenylsilane 

Downstream Products

• 18752-21-1 allyltriphenylsilane 

Relevant articles and documents

Transition-metal complexes corresponding to the insertion into a group 4B element-carbon bond. 3. Reactivity of complexes with unsaturated carbon-carbon bonds. Crystal structure of (η5-cyclopentadienyl)(triphenylgermyl) (η3-hexenyl) nitrosylmolybdenum

Anions of the type [(η5-C5H5)(CO)(L)(M4BPh 3)MT]- (L = CO, NO; M4B - Si, Ge, Sn; MT = Mn, Mo, W) react with allyl halides, affording neutral σ-bonded alkenyl derivatives. These new complexes can rearrange to η3-allyl complexes and also lose (allyl)M4B to give η2-allyl complexes. According to the nature of both the transition metal and the group 4B metal η1, η3, or η2 complexes are obtained. A mechanism for these successive reactions is proposed. Butenyl and hexenyl iodides also react with the anions, affording η1 complexes that can eliminate CO and rearrange to a η3 ligand as shown by X-ray structure determination.