90199-14-7

Basic information

• Product Name: 2-(4-Keto-cyclohexen-⁽¹⁾-yl)-ethylalkohol
• Synonyms: 2-(4-Keto-cyclohexen-⁽¹⁾-yl)-ethylalkohol
• CAS NO: 90199-14-7
• Molecular Weight: 140.182
• Mol File: 90199-14-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(4-Keto-cyclohexen-⁽¹⁾-yl)-ethylalkohol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-Keto-cyclohexen-⁽¹⁾-yl)-ethylalkohol(90199-14-7)
• EPA Substance Registry System: 2-(4-Keto-cyclohexen-⁽¹⁾-yl)-ethylalkohol(90199-14-7)

Safety Data

• Hazardous Substances Data: 90199-14-7(Hazardous Substances Data)

Upstream product

• 702-23-8 2-(4-Methoxyphenyl)ethanol 

Downstream Products

• 32863-02-8 2-(4-oxocyclohexyl)ethyl acetate 
• 1616766-78-9 2-(4-oxocyclohexyl)ethyl 4-chlorobenzoate 
• 628731-60-2 4-(2-(benzyloxy)ethyl)cyclohexan-1-one 
• 1616766-79-0 (R)-2-(4-oxocyclohex-2-en-1-yl)ethyl 4-chlorobenzoate 

Relevant articles and documents

Synthesis of polycyclic cyclobutane derivatives by tandem intramolecular Michael-aldol reaction under two complementary conditions: TBDMSOTf-Et3N and TMSI-(TMS)2NH

The treatment of αβ-unsaturated esters having a ketone function at an appropriate position with either TBDMSOTf in the presence of Et3N or TMSI in the presence of (TMS)2NH provided, via a tandem intramolecular Michael-aldol reaction sequence, several different types of cyclobutane derivatives. The two reaction conditions were complementary. Tricyclo[4.2.1.03,8]nonanes 34 and 55, tricyclo[5.1.104,8]nonane 40, tricyclo[5.4.0.03,7]undecane 51, tetracyclo[5.4.0.03,7.09,11]undecane 45, and the bicyclo[3.2.0]heptanes 56, 57, and 58, which have structures either partially or completely similar to those of endiandric acids A (1a), B (1b), and C (2), trihydroxydecipiadiene (3), lintenone (4), italicene (5), and filifolone (6), were stereoselectively synthesized by the tandem reaction.