90776-75-3

Basic information

• Product Name: Trifluoro-methanesulfonate3,5,5-trimethyl-2-phenyl-4,5-dihydro-oxazol-3-ium;
• CAS NO: 90776-75-3
• Molecular Weight: 339.336
• Mol File: 90776-75-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trifluoro-methanesulfonate3,5,5-trimethyl-2-phenyl-4,5-dihydro-oxazol-3-ium;(CAS DataBase Reference)
• NIST Chemistry Reference: Trifluoro-methanesulfonate3,5,5-trimethyl-2-phenyl-4,5-dihydro-oxazol-3-ium;(90776-75-3)
• EPA Substance Registry System: Trifluoro-methanesulfonate3,5,5-trimethyl-2-phenyl-4,5-dihydro-oxazol-3-ium;(90776-75-3)

Safety Data

• Hazardous Substances Data: 90776-75-3(Hazardous Substances Data)

Upstream product

• 33561-48-7 5,5-dimethyl-2-phenyl-4,5-dihydrooxazole 
• 333-27-7 methyl trifluoromethanesulfonate 

Downstream Products

• 57440-25-2 N-methyl N-(methyl-2 hydroxy-2)-propyl benzamide 
• 90776-85-5 2-{[(2-Hydroxy-2-methyl-propyl)-methyl-amino]-phenyl-methylene}-malonic acid diethyl ester 
• 90776-82-2 (E)-2-Cyano-3-[(2-hydroxy-2-methyl-propyl)-methyl-amino]-3-phenyl-acrylic acid ethyl ester 

Relevant articles and documents

CONDENSATION DU CYANOACETATE D'ETHYLE SODE SUR LES SELS D'IMINOETHERS CYCLIQUES. SYNTHESE DIRECTE DE DERIVES D'OXAZEPINE-1,4 ONE-7

Sodium ethylcyanoacetate was found to react exclusively at the 2-position of trifluormethanesulfonate 2-alkyl(aryl) 1,3-oxazolinium salts 2.In most cases, the reaction leads specifically to a new series of 5-alkyl(aryl) 6-cyano 2,3-dihydro 1,4-oxazepine 7-ones 3.This efficient one-step ring-enlargement process occurs at the oxazolidin stage.Structural parameters affecting the scope and limitations of this condensation are discussed.