91133-36-7

Basic information

• Product Name: 4-(ethylcarbamoyl)phenyl acetate
• Synonyms: 4-(ethylcarbamoyl)phenyl acetate
• CAS NO: 91133-36-7
• Molecular Weight: 207.229
• Mol File: 91133-36-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-(ethylcarbamoyl)phenyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(ethylcarbamoyl)phenyl acetate(91133-36-7)
• EPA Substance Registry System: 4-(ethylcarbamoyl)phenyl acetate(91133-36-7)

Safety Data

• Hazardous Substances Data: 91133-36-7(Hazardous Substances Data)

Upstream product

• 5796-97-4 bis(triethylsilyl) peroxide 
• 51074-95-4 4-(aminocarbonyl) phenylacetate 

Relevant articles and documents

Generation of alkyl radicals from alkylsilyl peroxides and their applications to C-N or C-O bond formations

This article describes a novel method for the generation of alkyl radicals from alkylsilyl peroxides and their applications to the Cu-catalyzed mono-N-alkylation of amides or arylamines, and to the O-alkylation of carboxylic acids. The use of alkylsilyl peroxides as alkyl radical sources includes the following synthetic advantages: i) various alkylsilyl peroxides can be readily synthesized from the corresponding alcohols and be stored at bench, and ii) a variety of alkyl radicals can be generated efficiently under mild conditions.

Alkylsilyl Peroxides as Alkylating Agents in the Copper-Catalyzed Selective Mono-N-Alkylation of Primary Amides and Arylamines

The copper-catalyzed selective mono-N-alkylation of primary amides or arylamines using alkylsilyl peroxides as alkylating agents is reported. The reaction proceeds under mild reaction conditions and exhibits a broad substrate scope with respect to the alkylsilyl peroxides, as well as to the primary amides and arylamines. Mechanistic studies suggest that the present reaction should proceed through a free-radical process that includes alkyl radicals generated from the alkylsilyl peroxides.